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In situ generation of N-unsubstituted imines from alkyl azides and their applications for imine transfer via copper catalysis
Although azides have been widely used in nitrene transfer reactions, in situ generation of N-H imines from azides for downstream transformations has rarely been explored. We report copper-mediated formation of N-unsubstituted aliphatic imines from easily available aliphatic azides using a customized...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Association for the Advancement of Science
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5550227/ https://www.ncbi.nlm.nih.gov/pubmed/28808683 http://dx.doi.org/10.1126/sciadv.1700826 |