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Mechanochemical borylation of aryldiazonium salts; merging light and ball milling
Merging of photo- and mechanochemical activation permitted studying the role of eosin Y in the borylation of aryldiazonium salts in a ball mill. Simultaneous neat grinding/irradiation of the reactants and the photocatalyst led to the formation of boronates in a molten state. On the other hand, the c...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Beilstein-Institut
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5550817/ https://www.ncbi.nlm.nih.gov/pubmed/28845189 http://dx.doi.org/10.3762/bjoc.13.144 |
| _version_ | 1783256191929942016 |
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| author | Hernández, José G |
| author_facet | Hernández, José G |
| author_sort | Hernández, José G |
| collection | PubMed |
| description | Merging of photo- and mechanochemical activation permitted studying the role of eosin Y in the borylation of aryldiazonium salts in a ball mill. Simultaneous neat grinding/irradiation of the reactants and the photocatalyst led to the formation of boronates in a molten state. On the other hand, the catalyst-free liquid-assisted grinding/irradiation reaction also led to product formation, featuring a direct photolysis pathway facilitated by substrate–solvent charge-transfer complex formation. |
| format | Online Article Text |
| id | pubmed-5550817 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2017 |
| publisher | Beilstein-Institut |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-55508172017-08-25 Mechanochemical borylation of aryldiazonium salts; merging light and ball milling Hernández, José G Beilstein J Org Chem Full Research Paper Merging of photo- and mechanochemical activation permitted studying the role of eosin Y in the borylation of aryldiazonium salts in a ball mill. Simultaneous neat grinding/irradiation of the reactants and the photocatalyst led to the formation of boronates in a molten state. On the other hand, the catalyst-free liquid-assisted grinding/irradiation reaction also led to product formation, featuring a direct photolysis pathway facilitated by substrate–solvent charge-transfer complex formation. Beilstein-Institut 2017-07-26 /pmc/articles/PMC5550817/ /pubmed/28845189 http://dx.doi.org/10.3762/bjoc.13.144 Text en Copyright © 2017, Hernández https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
| spellingShingle | Full Research Paper Hernández, José G Mechanochemical borylation of aryldiazonium salts; merging light and ball milling |
| title | Mechanochemical borylation of aryldiazonium salts; merging light and ball milling |
| title_full | Mechanochemical borylation of aryldiazonium salts; merging light and ball milling |
| title_fullStr | Mechanochemical borylation of aryldiazonium salts; merging light and ball milling |
| title_full_unstemmed | Mechanochemical borylation of aryldiazonium salts; merging light and ball milling |
| title_short | Mechanochemical borylation of aryldiazonium salts; merging light and ball milling |
| title_sort | mechanochemical borylation of aryldiazonium salts; merging light and ball milling |
| topic | Full Research Paper |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5550817/ https://www.ncbi.nlm.nih.gov/pubmed/28845189 http://dx.doi.org/10.3762/bjoc.13.144 |
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