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Reversible Protonated Resting State of the Nitrogenase Active Site

[Image: see text] Protonated states of the nitrogenase active site are mechanistically significant since substrate reduction is invariably accompanied by proton uptake. We report the low pH characterization by X-ray crystallography and EPR spectroscopy of the nitrogenase molybdenum iron (MoFe) prote...

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Detalles Bibliográficos
Autores principales: Morrison, Christine N., Spatzal, Thomas, Rees, Douglas C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5553094/
https://www.ncbi.nlm.nih.gov/pubmed/28692802
http://dx.doi.org/10.1021/jacs.7b05695

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