NMR and Rheological Study of Anion Size Influence on the Properties of Two Imidazolium-based Ionic Liquids

NMR self-diffusion and relaxation, coupled with viscosity, were used to study the properties and structure of two imidazolium-based ionic liquids, 1-ethyl-3-methylimidazolium acetate [C(2)MIM][OAc] and 1-ethyl-3-methylimidazolium octanoate [C(2)MIM][OOct]. The experimental results point to the forma...

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Autores principales: Green, Stephen M., Ries, Michael E., Moffat, Jamie, Budtova, Tatiana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5566215/
https://www.ncbi.nlm.nih.gov/pubmed/28827729
http://dx.doi.org/10.1038/s41598-017-09509-2
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author Green, Stephen M.
Ries, Michael E.
Moffat, Jamie
Budtova, Tatiana
author_facet Green, Stephen M.
Ries, Michael E.
Moffat, Jamie
Budtova, Tatiana
author_sort Green, Stephen M.
collection PubMed
description NMR self-diffusion and relaxation, coupled with viscosity, were used to study the properties and structure of two imidazolium-based ionic liquids, 1-ethyl-3-methylimidazolium acetate [C(2)MIM][OAc] and 1-ethyl-3-methylimidazolium octanoate [C(2)MIM][OOct]. The experimental results point to the formation of different types of aggregates in each ionic liquid. These aggregates are small and stable under flow and temperature in [C(2)MIM][OAc], whereas the aggregates are large and sensitive to flow and temperature in [C(2)MIM][OOct]. In the latter case the size of aggregates decreases both under flow and temperature increase.
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spelling pubmed-55662152017-08-23 NMR and Rheological Study of Anion Size Influence on the Properties of Two Imidazolium-based Ionic Liquids Green, Stephen M. Ries, Michael E. Moffat, Jamie Budtova, Tatiana Sci Rep Article NMR self-diffusion and relaxation, coupled with viscosity, were used to study the properties and structure of two imidazolium-based ionic liquids, 1-ethyl-3-methylimidazolium acetate [C(2)MIM][OAc] and 1-ethyl-3-methylimidazolium octanoate [C(2)MIM][OOct]. The experimental results point to the formation of different types of aggregates in each ionic liquid. These aggregates are small and stable under flow and temperature in [C(2)MIM][OAc], whereas the aggregates are large and sensitive to flow and temperature in [C(2)MIM][OOct]. In the latter case the size of aggregates decreases both under flow and temperature increase. Nature Publishing Group UK 2017-08-21 /pmc/articles/PMC5566215/ /pubmed/28827729 http://dx.doi.org/10.1038/s41598-017-09509-2 Text en © The Author(s) 2017 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Green, Stephen M.
Ries, Michael E.
Moffat, Jamie
Budtova, Tatiana
NMR and Rheological Study of Anion Size Influence on the Properties of Two Imidazolium-based Ionic Liquids
title NMR and Rheological Study of Anion Size Influence on the Properties of Two Imidazolium-based Ionic Liquids
title_full NMR and Rheological Study of Anion Size Influence on the Properties of Two Imidazolium-based Ionic Liquids
title_fullStr NMR and Rheological Study of Anion Size Influence on the Properties of Two Imidazolium-based Ionic Liquids
title_full_unstemmed NMR and Rheological Study of Anion Size Influence on the Properties of Two Imidazolium-based Ionic Liquids
title_short NMR and Rheological Study of Anion Size Influence on the Properties of Two Imidazolium-based Ionic Liquids
title_sort nmr and rheological study of anion size influence on the properties of two imidazolium-based ionic liquids
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5566215/
https://www.ncbi.nlm.nih.gov/pubmed/28827729
http://dx.doi.org/10.1038/s41598-017-09509-2
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