Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives

For the concept of aromaticity, energetic quantification is crucial. However, this has been elusive for excited-state (Baird) aromaticity. Here we report our serendipitous discovery of two nonplanar thiophene-fused chiral [4n]annulenes (Th4) COT (Saddle) and (Th6) CDH (Screw), which by computational...

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Detalles Bibliográficos
Autores principales: Ueda, Michihisa, Jorner, Kjell, Sung, Young Mo, Mori, Tadashi, Xiao, Qi, Kim, Dongho, Ottosson, Henrik, Aida, Takuzo, Itoh, Yoshimitsu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5570949/
https://www.ncbi.nlm.nih.gov/pubmed/28839142
http://dx.doi.org/10.1038/s41467-017-00382-1

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5570949/
https://www.ncbi.nlm.nih.gov/pubmed/28839142
http://dx.doi.org/10.1038/s41467-017-00382-1

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