Supramolecular polymerization of a ureidopyrimidinone‐based [2]catenane prepared via ring‐closing metathesis

The synthesis and supramolecular polymerization of a ureidopyrimidinone‐based Sauvage‐type [2]catenane is reported. The monomer synthesis explores many routes using the elegant metathesis catalysts of Bob Grubbs, yielding a catenane with one ureidopyrimidinone in each cycle. The supramolecular polym...

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Detalles Bibliográficos
Autores principales: Teunissen, Abraham J. P., Berrocal, José Augusto, Corbet, Christiaan H. W. A., Meijer, E. W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Rapid Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5575501/
https://www.ncbi.nlm.nih.gov/pubmed/28931969
http://dx.doi.org/10.1002/pola.28694
Descripción
Sumario:The synthesis and supramolecular polymerization of a ureidopyrimidinone‐based Sauvage‐type [2]catenane is reported. The monomer synthesis explores many routes using the elegant metathesis catalysts of Bob Grubbs, yielding a catenane with one ureidopyrimidinone in each cycle. The supramolecular polymer obtained features both mechanical bonds and quadruple hydrogen bonding connections. [Image: see text]

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