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The Effect of Temperature on Selectivity in the Oscillatory Mode of the Phenylacetylene Oxidative Carbonylation Reaction
Reaction temperature plays a major role in product selectivity in the oscillatory mode of the palladium‐catalyzed phenylacetylene oxidative carbonylation reaction. At 40 °C, dimethyl (2Z)‐2‐phenyl‐2‐butenedioate is the major product whereas at 0 °C the major product is 5,5‐dimethoxy‐3‐phenyl‐2(5H)‐f...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5575551/ https://www.ncbi.nlm.nih.gov/pubmed/28556572 http://dx.doi.org/10.1002/cphc.201700359 |