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Contamination-free graphene by chemical vapor deposition in quartz furnaces

Although the growth of graphene by chemical vapor deposition is a production technique that guarantees high crystallinity and superior electronic properties on large areas, it is still a challenge for manufacturers to efficiently scale up the production to the industrial scale. In this context, issu...

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Autores principales: Lisi, Nicola, Dikonimos, Theodoros, Buonocore, Francesco, Pittori, Martina, Mazzaro, Raffaello, Rizzoli, Rita, Marras, Sergio, Capasso, Andrea
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5577164/
https://www.ncbi.nlm.nih.gov/pubmed/28855680
http://dx.doi.org/10.1038/s41598-017-09811-z
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author Lisi, Nicola
Dikonimos, Theodoros
Buonocore, Francesco
Pittori, Martina
Mazzaro, Raffaello
Rizzoli, Rita
Marras, Sergio
Capasso, Andrea
author_facet Lisi, Nicola
Dikonimos, Theodoros
Buonocore, Francesco
Pittori, Martina
Mazzaro, Raffaello
Rizzoli, Rita
Marras, Sergio
Capasso, Andrea
author_sort Lisi, Nicola
collection PubMed
description Although the growth of graphene by chemical vapor deposition is a production technique that guarantees high crystallinity and superior electronic properties on large areas, it is still a challenge for manufacturers to efficiently scale up the production to the industrial scale. In this context, issues related to the purity and reproducibility of the graphene batches exist and need to be tackled. When graphene is grown in quartz furnaces, in particular, it is common to end up with samples contaminated by heterogeneous particles, which alter the growth mechanism and affect graphene’s properties. In this paper, we fully unveil the source of such contaminations and explain how they create during the growth process. We further propose a modification of the widely used quartz furnace configuration to fully suppress the sample contamination and obtain identical and clean graphene batches on large areas.
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spelling pubmed-55771642017-09-01 Contamination-free graphene by chemical vapor deposition in quartz furnaces Lisi, Nicola Dikonimos, Theodoros Buonocore, Francesco Pittori, Martina Mazzaro, Raffaello Rizzoli, Rita Marras, Sergio Capasso, Andrea Sci Rep Article Although the growth of graphene by chemical vapor deposition is a production technique that guarantees high crystallinity and superior electronic properties on large areas, it is still a challenge for manufacturers to efficiently scale up the production to the industrial scale. In this context, issues related to the purity and reproducibility of the graphene batches exist and need to be tackled. When graphene is grown in quartz furnaces, in particular, it is common to end up with samples contaminated by heterogeneous particles, which alter the growth mechanism and affect graphene’s properties. In this paper, we fully unveil the source of such contaminations and explain how they create during the growth process. We further propose a modification of the widely used quartz furnace configuration to fully suppress the sample contamination and obtain identical and clean graphene batches on large areas. Nature Publishing Group UK 2017-08-30 /pmc/articles/PMC5577164/ /pubmed/28855680 http://dx.doi.org/10.1038/s41598-017-09811-z Text en © The Author(s) 2017 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Lisi, Nicola
Dikonimos, Theodoros
Buonocore, Francesco
Pittori, Martina
Mazzaro, Raffaello
Rizzoli, Rita
Marras, Sergio
Capasso, Andrea
Contamination-free graphene by chemical vapor deposition in quartz furnaces
title Contamination-free graphene by chemical vapor deposition in quartz furnaces
title_full Contamination-free graphene by chemical vapor deposition in quartz furnaces
title_fullStr Contamination-free graphene by chemical vapor deposition in quartz furnaces
title_full_unstemmed Contamination-free graphene by chemical vapor deposition in quartz furnaces
title_short Contamination-free graphene by chemical vapor deposition in quartz furnaces
title_sort contamination-free graphene by chemical vapor deposition in quartz furnaces
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5577164/
https://www.ncbi.nlm.nih.gov/pubmed/28855680
http://dx.doi.org/10.1038/s41598-017-09811-z
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