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Copper-catalyzed oxidative C(sp(3))–H/C(sp(2))–H cross-coupling en route to carbocyclic rings
Copper-catalyzed selective coupling of C(sp(3))–H bonds with C(sp(2))–H bonds has been developed. An aniline module was used as a directing group to generate an aminyl radical, which selectively cleaves the secondary and tertiary C(sp(3))–H bonds via a 1,5-HAT process to forge six-membered carbocycl...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5577718/ https://www.ncbi.nlm.nih.gov/pubmed/28966775 http://dx.doi.org/10.1039/c7sc00250e |