Luminescent Properties of Zn and Mg Complexes on N-(2-Carboxyphenyl)salicylidenimine Basis

New zinc and magnesium complexes of N-(2-carboxyphenyl)salicylidenimine) were synthesized and structurally characterized by elemental analysis, FT-IR, and X-ray single-crystal analysis. These complexes exhibit tuneable luminescence in the solid state from blue to green by varying by metal ion and co...

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Autores principales: Gusev, Alexey, Braga, Elena, Shul’gin, Victor, Lyssenko, Konstantin, Eremenko, Igor, Samsonova, Lybov, Degtyarenko, Konstantin, Kopylova, Tatiana, Linert, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5578263/
https://www.ncbi.nlm.nih.gov/pubmed/28771205
http://dx.doi.org/10.3390/ma10080897
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author Gusev, Alexey
Braga, Elena
Shul’gin, Victor
Lyssenko, Konstantin
Eremenko, Igor
Samsonova, Lybov
Degtyarenko, Konstantin
Kopylova, Tatiana
Linert, Wolfgang
author_facet Gusev, Alexey
Braga, Elena
Shul’gin, Victor
Lyssenko, Konstantin
Eremenko, Igor
Samsonova, Lybov
Degtyarenko, Konstantin
Kopylova, Tatiana
Linert, Wolfgang
author_sort Gusev, Alexey
collection PubMed
description New zinc and magnesium complexes of N-(2-carboxyphenyl)salicylidenimine) were synthesized and structurally characterized by elemental analysis, FT-IR, and X-ray single-crystal analysis. These complexes exhibit tuneable luminescence in the solid state from blue to green by varying by metal ion and composition. Moreover, the quantum yields range from 0.11 to 0.41, while lifetimes were determined to be in the nanosecond timescale. Thermal analysis shows that these complexes exhibit good thermal stability and can therefore well be used as electroluminescent materials.
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spelling pubmed-55782632017-09-05 Luminescent Properties of Zn and Mg Complexes on N-(2-Carboxyphenyl)salicylidenimine Basis Gusev, Alexey Braga, Elena Shul’gin, Victor Lyssenko, Konstantin Eremenko, Igor Samsonova, Lybov Degtyarenko, Konstantin Kopylova, Tatiana Linert, Wolfgang Materials (Basel) Article New zinc and magnesium complexes of N-(2-carboxyphenyl)salicylidenimine) were synthesized and structurally characterized by elemental analysis, FT-IR, and X-ray single-crystal analysis. These complexes exhibit tuneable luminescence in the solid state from blue to green by varying by metal ion and composition. Moreover, the quantum yields range from 0.11 to 0.41, while lifetimes were determined to be in the nanosecond timescale. Thermal analysis shows that these complexes exhibit good thermal stability and can therefore well be used as electroluminescent materials. MDPI 2017-08-03 /pmc/articles/PMC5578263/ /pubmed/28771205 http://dx.doi.org/10.3390/ma10080897 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Gusev, Alexey
Braga, Elena
Shul’gin, Victor
Lyssenko, Konstantin
Eremenko, Igor
Samsonova, Lybov
Degtyarenko, Konstantin
Kopylova, Tatiana
Linert, Wolfgang
Luminescent Properties of Zn and Mg Complexes on N-(2-Carboxyphenyl)salicylidenimine Basis
title Luminescent Properties of Zn and Mg Complexes on N-(2-Carboxyphenyl)salicylidenimine Basis
title_full Luminescent Properties of Zn and Mg Complexes on N-(2-Carboxyphenyl)salicylidenimine Basis
title_fullStr Luminescent Properties of Zn and Mg Complexes on N-(2-Carboxyphenyl)salicylidenimine Basis
title_full_unstemmed Luminescent Properties of Zn and Mg Complexes on N-(2-Carboxyphenyl)salicylidenimine Basis
title_short Luminescent Properties of Zn and Mg Complexes on N-(2-Carboxyphenyl)salicylidenimine Basis
title_sort luminescent properties of zn and mg complexes on n-(2-carboxyphenyl)salicylidenimine basis
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5578263/
https://www.ncbi.nlm.nih.gov/pubmed/28771205
http://dx.doi.org/10.3390/ma10080897
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