Organosilica Membrane with Ionic Liquid Properties for Separation of Toluene/H(2) Mixture

In this study, we present a new concept in chemically stabilized ionic liquid membranes: an ionic liquid organosilica (ILOS) membrane, which is an organosilica membrane with ionic liquid-like properties. A silylated ionic liquid was used as a precursor for synthesis. The permselectivity, permeation...

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Detalles Bibliográficos
Autores principales: Hirota, Yuichiro, Maeda, Yohei, Yamamoto, Yusuke, Miyamoto, Manabu, Nishiyama, Norikazu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5578267/
https://www.ncbi.nlm.nih.gov/pubmed/28771202
http://dx.doi.org/10.3390/ma10080901
Descripción
Sumario:In this study, we present a new concept in chemically stabilized ionic liquid membranes: an ionic liquid organosilica (ILOS) membrane, which is an organosilica membrane with ionic liquid-like properties. A silylated ionic liquid was used as a precursor for synthesis. The permselectivity, permeation mechanism, and stability of the membrane in the H(2)/toluene binary system were then compared with a supported ionic liquid membrane. The membrane showed a superior separation factor of toluene/H(2) (>17,000) in a binary mixture system based on a solution–diffusion mechanism with improved durability over the supported ionic liquid membrane.

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