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Study of CeO(2) Modified AlNi Mixed Pillared Clays Supported Palladium Catalysts for Benzene Adsorption/Desorption-Catalytic Combustion
A new functional AlNi-pillared clays (AlNi-PILC) with a large surface area and pore volume was synthesized. The performance of adsorption/desorption-catalytic combustion over CeO(2-)modified Pd/AlNi-PILC catalysts was also studied. The results showed that the d(001)-value and specific surface area (...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5578315/ https://www.ncbi.nlm.nih.gov/pubmed/28809809 http://dx.doi.org/10.3390/ma10080949 |
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author | Li, Jingrong Zuo, Shufeng Yang, Peng Qi, Chenze |
author_facet | Li, Jingrong Zuo, Shufeng Yang, Peng Qi, Chenze |
author_sort | Li, Jingrong |
collection | PubMed |
description | A new functional AlNi-pillared clays (AlNi-PILC) with a large surface area and pore volume was synthesized. The performance of adsorption/desorption-catalytic combustion over CeO(2-)modified Pd/AlNi-PILC catalysts was also studied. The results showed that the d(001)-value and specific surface area (S(BET)) of AlNi-PILC reached 2.11 nm and 374.8 m(2)/g, respectively. The large S(BET) and the d(001)-value improved the high capacity for benzene adsorption. Also, the strong interaction between PdCe mixed oxides and AlNi-PILC led to the high dispersion of PdO and CeO(2) on the support, which was responsible for the high catalytic performance. Especially, 0.2% Pd/12.5% Ce/AlNi-PILC presented high performance for benzene combustion at 240 °C and high CO(2) selectivity. Also, the combustion temperatures were lower compared to the desorption temperatures, which demonstrated that it could accomplish benzene combustion during the desorption process. Furthermore, its activity did not decrease after continuous reaction for 1000 h in dry air, and it also displayed good resistance to water and the chlorinated compound, making it a promising catalytic material for the elimination of volatile organic compounds. |
format | Online Article Text |
id | pubmed-5578315 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-55783152017-09-05 Study of CeO(2) Modified AlNi Mixed Pillared Clays Supported Palladium Catalysts for Benzene Adsorption/Desorption-Catalytic Combustion Li, Jingrong Zuo, Shufeng Yang, Peng Qi, Chenze Materials (Basel) Article A new functional AlNi-pillared clays (AlNi-PILC) with a large surface area and pore volume was synthesized. The performance of adsorption/desorption-catalytic combustion over CeO(2-)modified Pd/AlNi-PILC catalysts was also studied. The results showed that the d(001)-value and specific surface area (S(BET)) of AlNi-PILC reached 2.11 nm and 374.8 m(2)/g, respectively. The large S(BET) and the d(001)-value improved the high capacity for benzene adsorption. Also, the strong interaction between PdCe mixed oxides and AlNi-PILC led to the high dispersion of PdO and CeO(2) on the support, which was responsible for the high catalytic performance. Especially, 0.2% Pd/12.5% Ce/AlNi-PILC presented high performance for benzene combustion at 240 °C and high CO(2) selectivity. Also, the combustion temperatures were lower compared to the desorption temperatures, which demonstrated that it could accomplish benzene combustion during the desorption process. Furthermore, its activity did not decrease after continuous reaction for 1000 h in dry air, and it also displayed good resistance to water and the chlorinated compound, making it a promising catalytic material for the elimination of volatile organic compounds. MDPI 2017-08-15 /pmc/articles/PMC5578315/ /pubmed/28809809 http://dx.doi.org/10.3390/ma10080949 Text en © 2017 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Li, Jingrong Zuo, Shufeng Yang, Peng Qi, Chenze Study of CeO(2) Modified AlNi Mixed Pillared Clays Supported Palladium Catalysts for Benzene Adsorption/Desorption-Catalytic Combustion |
title | Study of CeO(2) Modified AlNi Mixed Pillared Clays Supported Palladium Catalysts for Benzene Adsorption/Desorption-Catalytic Combustion |
title_full | Study of CeO(2) Modified AlNi Mixed Pillared Clays Supported Palladium Catalysts for Benzene Adsorption/Desorption-Catalytic Combustion |
title_fullStr | Study of CeO(2) Modified AlNi Mixed Pillared Clays Supported Palladium Catalysts for Benzene Adsorption/Desorption-Catalytic Combustion |
title_full_unstemmed | Study of CeO(2) Modified AlNi Mixed Pillared Clays Supported Palladium Catalysts for Benzene Adsorption/Desorption-Catalytic Combustion |
title_short | Study of CeO(2) Modified AlNi Mixed Pillared Clays Supported Palladium Catalysts for Benzene Adsorption/Desorption-Catalytic Combustion |
title_sort | study of ceo(2) modified alni mixed pillared clays supported palladium catalysts for benzene adsorption/desorption-catalytic combustion |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5578315/ https://www.ncbi.nlm.nih.gov/pubmed/28809809 http://dx.doi.org/10.3390/ma10080949 |
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