A Simple and Inexpensive Electrochemical Assay for the Identification of Nitrogen Containing Explosives in the Field

We report a simple and inexpensive electrochemical assay using a custom built hand-held potentiostat for the identification of explosives. The assay is based on a wipe test and is specifically designed for use in the field. The prototype instrument designed to run the assay is capable of performing...

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Detalles Bibliográficos
Autores principales: Erickson, Jeffrey S., Shriver-Lake, Lisa C., Zabetakis, Daniel, Stenger, David A., Trammell, Scott A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5579490/
https://www.ncbi.nlm.nih.gov/pubmed/28767088
http://dx.doi.org/10.3390/s17081769
Descripción
Sumario:We report a simple and inexpensive electrochemical assay using a custom built hand-held potentiostat for the identification of explosives. The assay is based on a wipe test and is specifically designed for use in the field. The prototype instrument designed to run the assay is capable of performing time-resolved electrochemical measurements including cyclic square wave voltammetry using an embedded microcontroller with parts costing roughly $250 USD. We generated an example library of cyclic square wave voltammograms of 12 compounds including 10 nitroaromatics, a nitramine (RDX), and a nitrate ester (nitroglycine), and designed a simple discrimination algorithm based on this library data for identification.

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