Cargando…
A Chlorinating Reagent Yields Vinyl Chlorides with High Regioselectivity under Heterogeneous Gold Catalysis
[Image: see text] A novel chlorinating reagent with a high concentration of HCl has enabled the highly regioselective hydrochlorination of unactivated alkynes using a commercial nanogold catalyst. No overchlorination or hydration products were formed, and various functional groups were tolerated. Th...
Autores principales: | Liang, Shengzong, Ebule, Rene, Hammond, Gerald B., Xu, Bo |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2017
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5586251/ https://www.ncbi.nlm.nih.gov/pubmed/28809497 http://dx.doi.org/10.1021/acs.orglett.7b02101 |
Ejemplares similares
-
Chloride-Tolerant Gold(I)-Catalyzed Regioselective
Hydrochlorination of Alkynes
por: Ebule, Rene, et al.
Publicado: (2017) -
Synthesis of Fulvene Vinyl Ethers by Gold Catalysis
por: Ahrens, Alexander, et al.
Publicado: (2020) -
Influence of Acetone and Primer on Strength and Ductility of Chlorinated Poly(vinyl chloride)
por: Mi, Hanlin, et al.
Publicado: (2023) -
Regioselective C–H
Thiocyanation of Arenes
by Iron(III) Chloride Catalysis
por: Waddell, Lachlan J. N., et al.
Publicado: (2023) -
Heterogeneous Gold Catalysis
por: Hutchings, Graham J.
Publicado: (2018)