Detection of σ-alkane complexes of manganese by NMR and IR spectroscopy in solution: (η(5)-C(5)H(5))Mn(CO)(2)(ethane) and (η(5)-C(5)H(5))Mn(CO)(2)(isopentane)

Irradiation of CpMn(CO)(3) in liquid ethane at 135 K at 355 nm yields a photoproduct that exhibits ν(CO) bands in the IR spectrum shifted to low wavenumber with respect to CpMn(CO)(3) that are indicative of a Mn(i) dicarbonyl. Parallel experiments employing in situ irradiation within an NMR probe (1...

Descripción completa

Detalles Bibliográficos
Autores principales: Torres, Olga, Calladine, James A., Duckett, Simon B., George, Michael W., Perutz, Robin N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5587984/
https://www.ncbi.nlm.nih.gov/pubmed/28936300
http://dx.doi.org/10.1039/c4sc02869d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5587984/
https://www.ncbi.nlm.nih.gov/pubmed/28936300
http://dx.doi.org/10.1039/c4sc02869d

Ejemplares similares