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Detection of σ-alkane complexes of manganese by NMR and IR spectroscopy in solution: (η(5)-C(5)H(5))Mn(CO)(2)(ethane) and (η(5)-C(5)H(5))Mn(CO)(2)(isopentane)

Irradiation of CpMn(CO)(3) in liquid ethane at 135 K at 355 nm yields a photoproduct that exhibits ν(CO) bands in the IR spectrum shifted to low wavenumber with respect to CpMn(CO)(3) that are indicative of a Mn(i) dicarbonyl. Parallel experiments employing in situ irradiation within an NMR probe (1...

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Detalles Bibliográficos
Autores principales:	Torres, Olga, Calladine, James A., Duckett, Simon B., George, Michael W., Perutz, Robin N.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5587984/ https://www.ncbi.nlm.nih.gov/pubmed/28936300 http://dx.doi.org/10.1039/c4sc02869d

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