Crystal structure of chlorido­(dimethyl sulfoxide-κS)bis­[4-(pyridin-2-yl)benzaldehyde-κ(3) C (2),N]iridium(III) aceto­nitrile monosolvate

The title compound, [IrCl(C(12)H(8)NO)(2){(CH(3))(2)SO}]·H(3)CCN or [IrCl(fppy)(2)(DMSO)]·H(3)CCN [where fppy is 4-(pyridin-2-yl)benzaldehyde and DMSO is dimethyl sulfoxide], is a mononuclear iridium(III) complex including two fppy ligands, a sulfur-coordinating DMSO ligand, and one terminal chlorid...

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Autores principales: Peloquin, Andrew J., Smith, Madelyn B., Balaich, Gary J., Iacono, Scott T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588560/
https://www.ncbi.nlm.nih.gov/pubmed/28932454
http://dx.doi.org/10.1107/S2056989017010945
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author Peloquin, Andrew J.
Smith, Madelyn B.
Balaich, Gary J.
Iacono, Scott T.
author_facet Peloquin, Andrew J.
Smith, Madelyn B.
Balaich, Gary J.
Iacono, Scott T.
author_sort Peloquin, Andrew J.
collection PubMed
description The title compound, [IrCl(C(12)H(8)NO)(2){(CH(3))(2)SO}]·H(3)CCN or [IrCl(fppy)(2)(DMSO)]·H(3)CCN [where fppy is 4-(pyridin-2-yl)benzaldehyde and DMSO is dimethyl sulfoxide], is a mononuclear iridium(III) complex including two fppy ligands, a sulfur-coordinating DMSO ligand, and one terminal chloride ligand that define a distorted octa­hedral coordination sphere. The complex crystallizes from 1:1 DMSO–aceto­nitrile as an aceto­nitrile solvate. In the crystal, weak C—H⋯O and C—H⋯N hydrogen-bonding inter­actions between adjacent complexes and between the aceto­nitrile solvent and the complex consolidate the packing.
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spelling pubmed-55885602017-09-20 Crystal structure of chlorido­(dimethyl sulfoxide-κS)bis­[4-(pyridin-2-yl)benzaldehyde-κ(3) C (2),N]iridium(III) aceto­nitrile monosolvate Peloquin, Andrew J. Smith, Madelyn B. Balaich, Gary J. Iacono, Scott T. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [IrCl(C(12)H(8)NO)(2){(CH(3))(2)SO}]·H(3)CCN or [IrCl(fppy)(2)(DMSO)]·H(3)CCN [where fppy is 4-(pyridin-2-yl)benzaldehyde and DMSO is dimethyl sulfoxide], is a mononuclear iridium(III) complex including two fppy ligands, a sulfur-coordinating DMSO ligand, and one terminal chloride ligand that define a distorted octa­hedral coordination sphere. The complex crystallizes from 1:1 DMSO–aceto­nitrile as an aceto­nitrile solvate. In the crystal, weak C—H⋯O and C—H⋯N hydrogen-bonding inter­actions between adjacent complexes and between the aceto­nitrile solvent and the complex consolidate the packing. International Union of Crystallography 2017-08-01 /pmc/articles/PMC5588560/ /pubmed/28932454 http://dx.doi.org/10.1107/S2056989017010945 Text en © Peloquin et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Peloquin, Andrew J.
Smith, Madelyn B.
Balaich, Gary J.
Iacono, Scott T.
Crystal structure of chlorido­(dimethyl sulfoxide-κS)bis­[4-(pyridin-2-yl)benzaldehyde-κ(3) C (2),N]iridium(III) aceto­nitrile monosolvate
title Crystal structure of chlorido­(dimethyl sulfoxide-κS)bis­[4-(pyridin-2-yl)benzaldehyde-κ(3) C (2),N]iridium(III) aceto­nitrile monosolvate
title_full Crystal structure of chlorido­(dimethyl sulfoxide-κS)bis­[4-(pyridin-2-yl)benzaldehyde-κ(3) C (2),N]iridium(III) aceto­nitrile monosolvate
title_fullStr Crystal structure of chlorido­(dimethyl sulfoxide-κS)bis­[4-(pyridin-2-yl)benzaldehyde-κ(3) C (2),N]iridium(III) aceto­nitrile monosolvate
title_full_unstemmed Crystal structure of chlorido­(dimethyl sulfoxide-κS)bis­[4-(pyridin-2-yl)benzaldehyde-κ(3) C (2),N]iridium(III) aceto­nitrile monosolvate
title_short Crystal structure of chlorido­(dimethyl sulfoxide-κS)bis­[4-(pyridin-2-yl)benzaldehyde-κ(3) C (2),N]iridium(III) aceto­nitrile monosolvate
title_sort crystal structure of chlorido­(dimethyl sulfoxide-κs)bis­[4-(pyridin-2-yl)benzaldehyde-κ(3) c (2),n]iridium(iii) aceto­nitrile monosolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588560/
https://www.ncbi.nlm.nih.gov/pubmed/28932454
http://dx.doi.org/10.1107/S2056989017010945
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