Synthesis and crystal structure of cerium(IV) bis­(phosphite)

The structure of cerium(IV) bis­(phosphite), Ce(HPO(3))(2), has been solved by single-crystal X-ray diffraction and has trigonal (P-3m1) symmetry. The cerium(IV) cation exhibits site symmetry -3m. and is octa­hedrally coordinated by O atoms of the phosphite ligands (point group symmetry 3m.). The hi...

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Detalles Bibliográficos
Autores principales: Byer, Stefano H., Villa, Eric M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588563/
https://www.ncbi.nlm.nih.gov/pubmed/28932457
http://dx.doi.org/10.1107/S205698901701115X
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author Byer, Stefano H.
Villa, Eric M.
author_facet Byer, Stefano H.
Villa, Eric M.
author_sort Byer, Stefano H.
collection PubMed
description The structure of cerium(IV) bis­(phosphite), Ce(HPO(3))(2), has been solved by single-crystal X-ray diffraction and has trigonal (P-3m1) symmetry. The cerium(IV) cation exhibits site symmetry -3m. and is octa­hedrally coordinated by O atoms of the phosphite ligands (point group symmetry 3m.). The highly symmetrical compound has a layered structure parallel to the ab plane, and is closely related to zirconium(IV) bis­(phosphite) solved via powder X-ray diffraction with trigonal (P-3 symmetry. Structural details of the two compounds are comparatively discussed.
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spelling pubmed-55885632017-09-20 Synthesis and crystal structure of cerium(IV) bis­(phosphite) Byer, Stefano H. Villa, Eric M. Acta Crystallogr E Crystallogr Commun Research Communications The structure of cerium(IV) bis­(phosphite), Ce(HPO(3))(2), has been solved by single-crystal X-ray diffraction and has trigonal (P-3m1) symmetry. The cerium(IV) cation exhibits site symmetry -3m. and is octa­hedrally coordinated by O atoms of the phosphite ligands (point group symmetry 3m.). The highly symmetrical compound has a layered structure parallel to the ab plane, and is closely related to zirconium(IV) bis­(phosphite) solved via powder X-ray diffraction with trigonal (P-3 symmetry. Structural details of the two compounds are comparatively discussed. International Union of Crystallography 2017-08-04 /pmc/articles/PMC5588563/ /pubmed/28932457 http://dx.doi.org/10.1107/S205698901701115X Text en © Byer and Villa 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Byer, Stefano H.
Villa, Eric M.
Synthesis and crystal structure of cerium(IV) bis­(phosphite)
title Synthesis and crystal structure of cerium(IV) bis­(phosphite)
title_full Synthesis and crystal structure of cerium(IV) bis­(phosphite)
title_fullStr Synthesis and crystal structure of cerium(IV) bis­(phosphite)
title_full_unstemmed Synthesis and crystal structure of cerium(IV) bis­(phosphite)
title_short Synthesis and crystal structure of cerium(IV) bis­(phosphite)
title_sort synthesis and crystal structure of cerium(iv) bis­(phosphite)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588563/
https://www.ncbi.nlm.nih.gov/pubmed/28932457
http://dx.doi.org/10.1107/S205698901701115X
work_keys_str_mv AT byerstefanoh synthesisandcrystalstructureofceriumivbisphosphite
AT villaericm synthesisandcrystalstructureofceriumivbisphosphite

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