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Crystal structure of the tetrahydrofuran disolvate of a 94:6 solid solution of [N (2),N (6)-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(II) and its monophosphine oxide analogue
The MnBr(2) complex of N (2),N (6)-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine (1·MnBr(2)) co-crystallizes with 5.69% of the monophosphine oxide analogue (1O·MnBr(2)) and two tetrahydrofuran (THF) molecules, namely [N (2),N (6)-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibrom...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588568/ https://www.ncbi.nlm.nih.gov/pubmed/28932462 http://dx.doi.org/10.1107/S2056989017011276 |
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author | Rotter, Markus Mastalir, Matthias Glatz, Mathias Stöger, Berthold Kirchner, Karl |
author_facet | Rotter, Markus Mastalir, Matthias Glatz, Mathias Stöger, Berthold Kirchner, Karl |
author_sort | Rotter, Markus |
collection | PubMed |
description | The MnBr(2) complex of N (2),N (6)-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine (1·MnBr(2)) co-crystallizes with 5.69% of the monophosphine oxide analogue (1O·MnBr(2)) and two tetrahydrofuran (THF) molecules, namely [N (2),N (6)-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(II)–[bis(di-tert-butylphosphanyl)({6-[(di-tert-butylphosphanyl)amino]pyridin-2-yl}amino)phosphine oxide]dibromidomanganese(II)–tetrahydrofuran (0.94/0.06/2), [MnBr(2)(C(21)H(41)N(3)P(2))](0.94)[MnBr(2)(C(21)H(41)N(3)OP(2))](0.06)·2C(4)H(8)O. The 1·MnBr(2) and 1O·MnBr(2) complexes are occupationally disordered about general positions. Both complexes feature square-pyramidal coordination of the Mn(II) atoms. They are connected by weak N—H⋯Br hydrogen bonding into chains extending along [001]. The THF molecules are located between the layers formed by these chains. One THF molecule is involved in hydrogen bonding to an amine H atom. |
format | Online Article Text |
id | pubmed-5588568 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-55885682017-09-20 Crystal structure of the tetrahydrofuran disolvate of a 94:6 solid solution of [N (2),N (6)-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(II) and its monophosphine oxide analogue Rotter, Markus Mastalir, Matthias Glatz, Mathias Stöger, Berthold Kirchner, Karl Acta Crystallogr E Crystallogr Commun Research Communications The MnBr(2) complex of N (2),N (6)-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine (1·MnBr(2)) co-crystallizes with 5.69% of the monophosphine oxide analogue (1O·MnBr(2)) and two tetrahydrofuran (THF) molecules, namely [N (2),N (6)-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(II)–[bis(di-tert-butylphosphanyl)({6-[(di-tert-butylphosphanyl)amino]pyridin-2-yl}amino)phosphine oxide]dibromidomanganese(II)–tetrahydrofuran (0.94/0.06/2), [MnBr(2)(C(21)H(41)N(3)P(2))](0.94)[MnBr(2)(C(21)H(41)N(3)OP(2))](0.06)·2C(4)H(8)O. The 1·MnBr(2) and 1O·MnBr(2) complexes are occupationally disordered about general positions. Both complexes feature square-pyramidal coordination of the Mn(II) atoms. They are connected by weak N—H⋯Br hydrogen bonding into chains extending along [001]. The THF molecules are located between the layers formed by these chains. One THF molecule is involved in hydrogen bonding to an amine H atom. International Union of Crystallography 2017-08-08 /pmc/articles/PMC5588568/ /pubmed/28932462 http://dx.doi.org/10.1107/S2056989017011276 Text en © Rotter et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Rotter, Markus Mastalir, Matthias Glatz, Mathias Stöger, Berthold Kirchner, Karl Crystal structure of the tetrahydrofuran disolvate of a 94:6 solid solution of [N (2),N (6)-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(II) and its monophosphine oxide analogue |
title | Crystal structure of the tetrahydrofuran disolvate of a 94:6 solid solution of [N
(2),N
(6)-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(II) and its monophosphine oxide analogue |
title_full | Crystal structure of the tetrahydrofuran disolvate of a 94:6 solid solution of [N
(2),N
(6)-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(II) and its monophosphine oxide analogue |
title_fullStr | Crystal structure of the tetrahydrofuran disolvate of a 94:6 solid solution of [N
(2),N
(6)-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(II) and its monophosphine oxide analogue |
title_full_unstemmed | Crystal structure of the tetrahydrofuran disolvate of a 94:6 solid solution of [N
(2),N
(6)-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(II) and its monophosphine oxide analogue |
title_short | Crystal structure of the tetrahydrofuran disolvate of a 94:6 solid solution of [N
(2),N
(6)-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(II) and its monophosphine oxide analogue |
title_sort | crystal structure of the tetrahydrofuran disolvate of a 94:6 solid solution of [n
(2),n
(6)-bis(di-tert-butylphosphanyl)pyridine-2,6-diamine]dibromidomanganese(ii) and its monophosphine oxide analogue |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588568/ https://www.ncbi.nlm.nih.gov/pubmed/28932462 http://dx.doi.org/10.1107/S2056989017011276 |
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