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Crystal structure of (E)-furan-2-carbaldehyde O-benzoyloxime
In the title compound, C(12)H(9)NO(3), the benzoate and furan rings are almost coplanar, making a dihedral angle of 11.68 (9)°. The twist angle between the –COO group and the benzene ring is only 2.79 (16)°. In the crystal, molecules are linked by C—H⋯O hydrogen bonds, forming chains along [100]. T...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588572/ https://www.ncbi.nlm.nih.gov/pubmed/28932466 http://dx.doi.org/10.1107/S2056989017011562 |
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author | Hijji, Yousef M. Rajan, Rajeesha Mansour, Said Ben Yahia, Hamdi |
author_facet | Hijji, Yousef M. Rajan, Rajeesha Mansour, Said Ben Yahia, Hamdi |
author_sort | Hijji, Yousef M. |
collection | PubMed |
description | In the title compound, C(12)H(9)NO(3), the benzoate and furan rings are almost coplanar, making a dihedral angle of 11.68 (9)°. The twist angle between the –COO group and the benzene ring is only 2.79 (16)°. In the crystal, molecules are linked by C—H⋯O hydrogen bonds, forming chains along [100]. The molecules stack in a herringbone fashion and inversion-related chains are linked by offset π–π interactions [intercentroid distance = 3.931 (1) Å], forming ribbons propagating along the a-axis direction. |
format | Online Article Text |
id | pubmed-5588572 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-55885722017-09-20 Crystal structure of (E)-furan-2-carbaldehyde O-benzoyloxime Hijji, Yousef M. Rajan, Rajeesha Mansour, Said Ben Yahia, Hamdi Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(12)H(9)NO(3), the benzoate and furan rings are almost coplanar, making a dihedral angle of 11.68 (9)°. The twist angle between the –COO group and the benzene ring is only 2.79 (16)°. In the crystal, molecules are linked by C—H⋯O hydrogen bonds, forming chains along [100]. The molecules stack in a herringbone fashion and inversion-related chains are linked by offset π–π interactions [intercentroid distance = 3.931 (1) Å], forming ribbons propagating along the a-axis direction. International Union of Crystallography 2017-08-08 /pmc/articles/PMC5588572/ /pubmed/28932466 http://dx.doi.org/10.1107/S2056989017011562 Text en © Hijji et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Hijji, Yousef M. Rajan, Rajeesha Mansour, Said Ben Yahia, Hamdi Crystal structure of (E)-furan-2-carbaldehyde O-benzoyloxime |
title | Crystal structure of (E)-furan-2-carbaldehyde O-benzoyloxime |
title_full | Crystal structure of (E)-furan-2-carbaldehyde O-benzoyloxime |
title_fullStr | Crystal structure of (E)-furan-2-carbaldehyde O-benzoyloxime |
title_full_unstemmed | Crystal structure of (E)-furan-2-carbaldehyde O-benzoyloxime |
title_short | Crystal structure of (E)-furan-2-carbaldehyde O-benzoyloxime |
title_sort | crystal structure of (e)-furan-2-carbaldehyde o-benzoyloxime |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588572/ https://www.ncbi.nlm.nih.gov/pubmed/28932466 http://dx.doi.org/10.1107/S2056989017011562 |
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