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Bis(μ-N,N-diallyldithiocarbamato)bis[(N,N-diallyldithiocarbamato)cadmium]
The title compound, [Cd(2)(C(7)H(10)NS(2))(4)], is a neutral dinuclear cadmium(II) complex bearing four bis N,N-diallyldithiocarbamate ligands coordinating to two Cd(II) cations. In each of the monomeric subunits, there are four S atoms of two dithiocarbamate ligands [Cd—S = 2.5558 (3), 2.8016...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588579/ https://www.ncbi.nlm.nih.gov/pubmed/28932473 http://dx.doi.org/10.1107/S2056989017011616 |
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author | Onwudiwe, Damian C. Hrubaru, Madalina Hosten, Eric C. Arderne, Charmaine |
author_facet | Onwudiwe, Damian C. Hrubaru, Madalina Hosten, Eric C. Arderne, Charmaine |
author_sort | Onwudiwe, Damian C. |
collection | PubMed |
description | The title compound, [Cd(2)(C(7)H(10)NS(2))(4)], is a neutral dinuclear cadmium(II) complex bearing four bis N,N-diallyldithiocarbamate ligands coordinating to two Cd(II) cations. In each of the monomeric subunits, there are four S atoms of two dithiocarbamate ligands [Cd—S = 2.5558 (3), 2.8016 (3), 2.6050 (3) and 2.5709 (3) Å] that coordinate to one Cd(II) atom in a bidentate mode. The dimers are located over an inversion centre bridged by two additional bridging Cd—S bonds [2.6021 (3) Å], leading to a substantial distortion of the geometry of the monomeric subunit from the expected square-planar geometry. The five-coordinate environment around each of the Cd(II) ions in the dimer is best described as substantially tetragonally distorted square pyramidal. The dithiocarbamate groups are themselves planar and are also coplanar with the Cd(II) ions. The negative charge on these groups is delocalized by resonance across the S atoms bound to the Cd(II) cation. This delocalization of the π electrons in the dithiocarbamate groups also extends to the C—N bonds as they reveal significant double bond character [C—N = 1.3213 (16) and 1.3333 (15) Å]. |
format | Online Article Text |
id | pubmed-5588579 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-55885792017-09-20 Bis(μ-N,N-diallyldithiocarbamato)bis[(N,N-diallyldithiocarbamato)cadmium] Onwudiwe, Damian C. Hrubaru, Madalina Hosten, Eric C. Arderne, Charmaine Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Cd(2)(C(7)H(10)NS(2))(4)], is a neutral dinuclear cadmium(II) complex bearing four bis N,N-diallyldithiocarbamate ligands coordinating to two Cd(II) cations. In each of the monomeric subunits, there are four S atoms of two dithiocarbamate ligands [Cd—S = 2.5558 (3), 2.8016 (3), 2.6050 (3) and 2.5709 (3) Å] that coordinate to one Cd(II) atom in a bidentate mode. The dimers are located over an inversion centre bridged by two additional bridging Cd—S bonds [2.6021 (3) Å], leading to a substantial distortion of the geometry of the monomeric subunit from the expected square-planar geometry. The five-coordinate environment around each of the Cd(II) ions in the dimer is best described as substantially tetragonally distorted square pyramidal. The dithiocarbamate groups are themselves planar and are also coplanar with the Cd(II) ions. The negative charge on these groups is delocalized by resonance across the S atoms bound to the Cd(II) cation. This delocalization of the π electrons in the dithiocarbamate groups also extends to the C—N bonds as they reveal significant double bond character [C—N = 1.3213 (16) and 1.3333 (15) Å]. International Union of Crystallography 2017-08-21 /pmc/articles/PMC5588579/ /pubmed/28932473 http://dx.doi.org/10.1107/S2056989017011616 Text en © Onwudiwe et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Onwudiwe, Damian C. Hrubaru, Madalina Hosten, Eric C. Arderne, Charmaine Bis(μ-N,N-diallyldithiocarbamato)bis[(N,N-diallyldithiocarbamato)cadmium] |
title | Bis(μ-N,N-diallyldithiocarbamato)bis[(N,N-diallyldithiocarbamato)cadmium] |
title_full | Bis(μ-N,N-diallyldithiocarbamato)bis[(N,N-diallyldithiocarbamato)cadmium] |
title_fullStr | Bis(μ-N,N-diallyldithiocarbamato)bis[(N,N-diallyldithiocarbamato)cadmium] |
title_full_unstemmed | Bis(μ-N,N-diallyldithiocarbamato)bis[(N,N-diallyldithiocarbamato)cadmium] |
title_short | Bis(μ-N,N-diallyldithiocarbamato)bis[(N,N-diallyldithiocarbamato)cadmium] |
title_sort | bis(μ-n,n-diallyldithiocarbamato)bis[(n,n-diallyldithiocarbamato)cadmium] |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588579/ https://www.ncbi.nlm.nih.gov/pubmed/28932473 http://dx.doi.org/10.1107/S2056989017011616 |
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