Crystal structure and DFT study of bis­{(S)-2-[(2-hy­droxy­benzyl)­amino]-4-methyl­penta­noato-κ(2) N,O}(1,10-phenanthroline-κ(2) N,N′)nickel(II)

In the title compound, [Ni(C(13)H(18)NO(3))(2)(C(12)H(8)N(2))], the Ni(II) cation shows a distorted octa­hedral coordination environment. It is formed by two N atoms from the phenanthroline ligand, as well as two N and two O atoms belonging to two 2-[(2-hy­droxy­benz­yl)amino]-4-methyl­penta­noate l...

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Detalles Bibliográficos
Autores principales: Faizi, Md. Serajul Haque, Dege, Necmi, Malinkin, Sergey
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588589/
https://www.ncbi.nlm.nih.gov/pubmed/28932483
http://dx.doi.org/10.1107/S2056989017012014
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author Faizi, Md. Serajul Haque
Dege, Necmi
Malinkin, Sergey
author_facet Faizi, Md. Serajul Haque
Dege, Necmi
Malinkin, Sergey
author_sort Faizi, Md. Serajul Haque
collection PubMed
description In the title compound, [Ni(C(13)H(18)NO(3))(2)(C(12)H(8)N(2))], the Ni(II) cation shows a distorted octa­hedral coordination environment. It is formed by two N atoms from the phenanthroline ligand, as well as two N and two O atoms belonging to two 2-[(2-hy­droxy­benz­yl)amino]-4-methyl­penta­noate ligands. Complex mol­ecules are connected into layers propagating along the ab plane via hydrogen bonds formed by O atoms of carboxyl­ate and phenoxide groups, which are further connected into a three-dimensional motif.
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spelling pubmed-55885892017-09-20 Crystal structure and DFT study of bis­{(S)-2-[(2-hy­droxy­benzyl)­amino]-4-methyl­penta­noato-κ(2) N,O}(1,10-phenanthroline-κ(2) N,N′)nickel(II) Faizi, Md. Serajul Haque Dege, Necmi Malinkin, Sergey Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Ni(C(13)H(18)NO(3))(2)(C(12)H(8)N(2))], the Ni(II) cation shows a distorted octa­hedral coordination environment. It is formed by two N atoms from the phenanthroline ligand, as well as two N and two O atoms belonging to two 2-[(2-hy­droxy­benz­yl)amino]-4-methyl­penta­noate ligands. Complex mol­ecules are connected into layers propagating along the ab plane via hydrogen bonds formed by O atoms of carboxyl­ate and phenoxide groups, which are further connected into a three-dimensional motif. International Union of Crystallography 2017-08-30 /pmc/articles/PMC5588589/ /pubmed/28932483 http://dx.doi.org/10.1107/S2056989017012014 Text en © Faizi et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Faizi, Md. Serajul Haque
Dege, Necmi
Malinkin, Sergey
Crystal structure and DFT study of bis­{(S)-2-[(2-hy­droxy­benzyl)­amino]-4-methyl­penta­noato-κ(2) N,O}(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title Crystal structure and DFT study of bis­{(S)-2-[(2-hy­droxy­benzyl)­amino]-4-methyl­penta­noato-κ(2) N,O}(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title_full Crystal structure and DFT study of bis­{(S)-2-[(2-hy­droxy­benzyl)­amino]-4-methyl­penta­noato-κ(2) N,O}(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title_fullStr Crystal structure and DFT study of bis­{(S)-2-[(2-hy­droxy­benzyl)­amino]-4-methyl­penta­noato-κ(2) N,O}(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title_full_unstemmed Crystal structure and DFT study of bis­{(S)-2-[(2-hy­droxy­benzyl)­amino]-4-methyl­penta­noato-κ(2) N,O}(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title_short Crystal structure and DFT study of bis­{(S)-2-[(2-hy­droxy­benzyl)­amino]-4-methyl­penta­noato-κ(2) N,O}(1,10-phenanthroline-κ(2) N,N′)nickel(II)
title_sort crystal structure and dft study of bis­{(s)-2-[(2-hy­droxy­benzyl)­amino]-4-methyl­penta­noato-κ(2) n,o}(1,10-phenanthroline-κ(2) n,n′)nickel(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588589/
https://www.ncbi.nlm.nih.gov/pubmed/28932483
http://dx.doi.org/10.1107/S2056989017012014
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