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Crystal structure of 1-[2-(4-nitro­phen­yl)-4,5-diphenyl-1H-imidazol-1-yl]propan-2-ol

The title compound, C(24)H(21)N(3)O(3), crystallizes with two unique but closely r.m.s. overlay fit = 0.215 Å) comparable mol­ecules (1 and 2) in the asymmetric unit of the triclinic unit cell. In molecule 1, the dihedral angles between the central imidazlole ring and the benzene-ring substituents a...

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Autores principales: Simpson, Jim, Mohamed, Shaaban K., Marzouk, Adel A., Abdelhamid, Antar A., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588590/
https://www.ncbi.nlm.nih.gov/pubmed/28932484
http://dx.doi.org/10.1107/S2056989017011057
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author Simpson, Jim
Mohamed, Shaaban K.
Marzouk, Adel A.
Abdelhamid, Antar A.
Albayati, Mustafa R.
author_facet Simpson, Jim
Mohamed, Shaaban K.
Marzouk, Adel A.
Abdelhamid, Antar A.
Albayati, Mustafa R.
author_sort Simpson, Jim
collection PubMed
description The title compound, C(24)H(21)N(3)O(3), crystallizes with two unique but closely r.m.s. overlay fit = 0.215 Å) comparable mol­ecules (1 and 2) in the asymmetric unit of the triclinic unit cell. In molecule 1, the dihedral angles between the central imidazlole ring and the benzene-ring substituents are 42.51 (9), 45.41 (9) and 56.92 (8)°, respectively. Comparable data for molecule 2 are 39.36 (10), 34.45 (11) and 60.34 (8)°, respectively. The rings at the 2-positions carry p-nitro substituents that subtend dihedral angles of 12.9 (4)° in mol­ecule 1 and 11.7 (4)° in mol­ecule 2 to their respective benzene ring planes. The imidazole rings also have propan-2-ol substituents on the 1-N atoms, which adopt extended conformations for the N—C—C—C chains. In the crystal, classical O—H⋯N hydrogen bonds combine with C—H⋯O, C—H⋯N and C—H⋯π(ring) hydrogen bonds and stack the molecules along the a-axis direction.
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spelling pubmed-55885902017-09-20 Crystal structure of 1-[2-(4-nitro­phen­yl)-4,5-diphenyl-1H-imidazol-1-yl]propan-2-ol Simpson, Jim Mohamed, Shaaban K. Marzouk, Adel A. Abdelhamid, Antar A. Albayati, Mustafa R. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(24)H(21)N(3)O(3), crystallizes with two unique but closely r.m.s. overlay fit = 0.215 Å) comparable mol­ecules (1 and 2) in the asymmetric unit of the triclinic unit cell. In molecule 1, the dihedral angles between the central imidazlole ring and the benzene-ring substituents are 42.51 (9), 45.41 (9) and 56.92 (8)°, respectively. Comparable data for molecule 2 are 39.36 (10), 34.45 (11) and 60.34 (8)°, respectively. The rings at the 2-positions carry p-nitro substituents that subtend dihedral angles of 12.9 (4)° in mol­ecule 1 and 11.7 (4)° in mol­ecule 2 to their respective benzene ring planes. The imidazole rings also have propan-2-ol substituents on the 1-N atoms, which adopt extended conformations for the N—C—C—C chains. In the crystal, classical O—H⋯N hydrogen bonds combine with C—H⋯O, C—H⋯N and C—H⋯π(ring) hydrogen bonds and stack the molecules along the a-axis direction. International Union of Crystallography 2017-08-30 /pmc/articles/PMC5588590/ /pubmed/28932484 http://dx.doi.org/10.1107/S2056989017011057 Text en © Simpson et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Simpson, Jim
Mohamed, Shaaban K.
Marzouk, Adel A.
Abdelhamid, Antar A.
Albayati, Mustafa R.
Crystal structure of 1-[2-(4-nitro­phen­yl)-4,5-diphenyl-1H-imidazol-1-yl]propan-2-ol
title Crystal structure of 1-[2-(4-nitro­phen­yl)-4,5-diphenyl-1H-imidazol-1-yl]propan-2-ol
title_full Crystal structure of 1-[2-(4-nitro­phen­yl)-4,5-diphenyl-1H-imidazol-1-yl]propan-2-ol
title_fullStr Crystal structure of 1-[2-(4-nitro­phen­yl)-4,5-diphenyl-1H-imidazol-1-yl]propan-2-ol
title_full_unstemmed Crystal structure of 1-[2-(4-nitro­phen­yl)-4,5-diphenyl-1H-imidazol-1-yl]propan-2-ol
title_short Crystal structure of 1-[2-(4-nitro­phen­yl)-4,5-diphenyl-1H-imidazol-1-yl]propan-2-ol
title_sort crystal structure of 1-[2-(4-nitro­phen­yl)-4,5-diphenyl-1h-imidazol-1-yl]propan-2-ol
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588590/
https://www.ncbi.nlm.nih.gov/pubmed/28932484
http://dx.doi.org/10.1107/S2056989017011057
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