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Electrochemical study of a nonheme Fe(ii) complex in the presence of dioxygen. Insights into the reductive activation of O(2) at Fe(ii) centers

Recent efforts to model the reactivity of iron oxygenases have led to the generation of nonheme Fe(III)(OOH) and Fe(IV)(O) intermediates from Fe(II) complexes and O(2) but using different cofactors. This diversity emphasizes the rich chemistry of nonheme Fe(ii) complexes with dioxygen. We report an...

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Detalles Bibliográficos
Autores principales:	Ségaud, Nathalie, Anxolabéhère-Mallart, Elodie, Sénéchal-David, Katell, Acosta-Rueda, Laura, Robert, Marc, Banse, Frédéric
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5588783/ https://www.ncbi.nlm.nih.gov/pubmed/28936313 http://dx.doi.org/10.1039/c4sc01891e

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