Crystal structure of [N,N-bis­(di­phenyl­phospho­ro­thio­yl)amidato-κ(2) S,S′]bis­(tri­phenyl­phosphane-κP)copper(I) di­chloro­methane monosolvate

The title compound, [Cu(C(24)H(20)NP(2)S(2))(C(18)H(15)P)(2)]·CH(2)Cl(2) or [Cu(dppaS(2))(PPh(3))(2)]·CH(2)Cl(2), is a neutral mononuclear copper(I) complex bearing an N,N-bis­(di­phenyl­phospho­rothio­yl)amidate (dppaS(2) (−)) ligand and two tri­phenyl­phosphane ligands. The molecular structure sho...

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Detalles Bibliográficos
Autores principales: Nishi, Tatsuya, Tsukuda, Toshiaki, Nishikawa, Michihiro, Tsubomura, Taro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598827/
https://www.ncbi.nlm.nih.gov/pubmed/28932415
http://dx.doi.org/10.1107/S2056989017009380
Descripción
Sumario:The title compound, [Cu(C(24)H(20)NP(2)S(2))(C(18)H(15)P)(2)]·CH(2)Cl(2) or [Cu(dppaS(2))(PPh(3))(2)]·CH(2)Cl(2), is a neutral mononuclear copper(I) complex bearing an N,N-bis­(di­phenyl­phospho­rothio­yl)amidate (dppaS(2) (−)) ligand and two tri­phenyl­phosphane ligands. The molecular structure shows that the two S atoms of the dppaS(2) (−) ligand [Cu—S = 2.3462 (9) and 2.3484 (9) Å] and the two P atoms of the two tri­phenyl­phosphane ligands [Cu—P = 2.3167 (9) and 2.2969 (9) Å] coordinate to the copper(I) atom, resulting in a tetra­hedral coordination geometry. The crystallographically observed mol­ecular structure is compared to the results of DFT calculations.

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