Tris(μ(2)-methano­lato)-μ(3)-oxido-tris­{[(E)-4-chloro-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)pheno­lato]manganese(III)} perchlorate–di­chloro­methane–diethyl ether (1/1.1/0.9)

In the title compound, [Mn(3)(C(14)H(12)ClN(2)O)(3)(CH(3)O)(3)O]ClO(4)·1.1CH(2)Cl(2)·0.9C(4)H(10)O, the cation consists of a central Mn(3)O core with μ(2)-methano­late bridging between adjacent Mn(III) atoms, thus giving each Mn(III) atom a mer-O(3) coordination environment. Six-coordination for eac...

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Detalles Bibliográficos
Autores principales: Egekenze, Rita, Gultneh, Yilma, Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598829/
https://www.ncbi.nlm.nih.gov/pubmed/28932417
http://dx.doi.org/10.1107/S2056989017008982
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author Egekenze, Rita
Gultneh, Yilma
Butcher, Ray J.
author_facet Egekenze, Rita
Gultneh, Yilma
Butcher, Ray J.
author_sort Egekenze, Rita
collection PubMed
description In the title compound, [Mn(3)(C(14)H(12)ClN(2)O)(3)(CH(3)O)(3)O]ClO(4)·1.1CH(2)Cl(2)·0.9C(4)H(10)O, the cation consists of a central Mn(3)O core with μ(2)-methano­late bridging between adjacent Mn(III) atoms, thus giving each Mn(III) atom a mer-O(3) coordination environment. Six-coordination for each Mn(III) atom is provided by the deprotonated Schiff base ligand (E)-4-chloro-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)phenolate. There are extensive C—H⋯O and C—H⋯Cl inter­actions, which link the cations, anions, and solvent mol­ecules into a three-dimensional array.
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spelling pubmed-55988292017-09-20 Tris(μ(2)-methano­lato)-μ(3)-oxido-tris­{[(E)-4-chloro-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)pheno­lato]manganese(III)} perchlorate–di­chloro­methane–diethyl ether (1/1.1/0.9) Egekenze, Rita Gultneh, Yilma Butcher, Ray J. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Mn(3)(C(14)H(12)ClN(2)O)(3)(CH(3)O)(3)O]ClO(4)·1.1CH(2)Cl(2)·0.9C(4)H(10)O, the cation consists of a central Mn(3)O core with μ(2)-methano­late bridging between adjacent Mn(III) atoms, thus giving each Mn(III) atom a mer-O(3) coordination environment. Six-coordination for each Mn(III) atom is provided by the deprotonated Schiff base ligand (E)-4-chloro-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)phenolate. There are extensive C—H⋯O and C—H⋯Cl inter­actions, which link the cations, anions, and solvent mol­ecules into a three-dimensional array. International Union of Crystallography 2017-07-04 /pmc/articles/PMC5598829/ /pubmed/28932417 http://dx.doi.org/10.1107/S2056989017008982 Text en © Egekenze et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Egekenze, Rita
Gultneh, Yilma
Butcher, Ray J.
Tris(μ(2)-methano­lato)-μ(3)-oxido-tris­{[(E)-4-chloro-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)pheno­lato]manganese(III)} perchlorate–di­chloro­methane–diethyl ether (1/1.1/0.9)
title Tris(μ(2)-methano­lato)-μ(3)-oxido-tris­{[(E)-4-chloro-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)pheno­lato]manganese(III)} perchlorate–di­chloro­methane–diethyl ether (1/1.1/0.9)
title_full Tris(μ(2)-methano­lato)-μ(3)-oxido-tris­{[(E)-4-chloro-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)pheno­lato]manganese(III)} perchlorate–di­chloro­methane–diethyl ether (1/1.1/0.9)
title_fullStr Tris(μ(2)-methano­lato)-μ(3)-oxido-tris­{[(E)-4-chloro-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)pheno­lato]manganese(III)} perchlorate–di­chloro­methane–diethyl ether (1/1.1/0.9)
title_full_unstemmed Tris(μ(2)-methano­lato)-μ(3)-oxido-tris­{[(E)-4-chloro-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)pheno­lato]manganese(III)} perchlorate–di­chloro­methane–diethyl ether (1/1.1/0.9)
title_short Tris(μ(2)-methano­lato)-μ(3)-oxido-tris­{[(E)-4-chloro-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)pheno­lato]manganese(III)} perchlorate–di­chloro­methane–diethyl ether (1/1.1/0.9)
title_sort tris(μ(2)-methano­lato)-μ(3)-oxido-tris­{[(e)-4-chloro-2-({[2-(pyridin-2-yl)eth­yl]imino}­meth­yl)pheno­lato]manganese(iii)} perchlorate–di­chloro­methane–diethyl ether (1/1.1/0.9)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598829/
https://www.ncbi.nlm.nih.gov/pubmed/28932417
http://dx.doi.org/10.1107/S2056989017008982
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AT butcherrayj trism2methanolatom3oxidotrise4chloro22pyridin2ylethyliminomethylphenolatomanganeseiiiperchloratedichloromethanediethylether11109

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