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Crystal structure of triphenylphosphoniummethylenetrifluoroborate
The title compound, C(19)H(17)BF(3)P {alternative name: triphenyl[(trifluoroboranyl)methyl]phosphanium}, was formed by the reaction of triphenylphosphine with potassium iodomethyltrifluoroborate. The molecule features a nearly staggered conformation along the P—C bond and a less than sta...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598835/ https://www.ncbi.nlm.nih.gov/pubmed/28932423 http://dx.doi.org/10.1107/S2056989017009884 |
Sumario: | The title compound, C(19)H(17)BF(3)P {alternative name: triphenyl[(trifluoroboranyl)methyl]phosphanium}, was formed by the reaction of triphenylphosphine with potassium iodomethyltrifluoroborate. The molecule features a nearly staggered conformation along the P—C bond and a less than staggered conformation along the C—B bond. In the crystal, weak C—H⋯F hydrogen bonds between the meta-phenyl C—H groups and the trifluoroborate B—F groups form chains of R (2) (2)(16) rings along [100]. These chains are are further stabilized by weak C—H⋯π interactions. A weak intramolecular C—H⋯F hydrogen bond is also observed. |
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