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Crystal structure of triphenylphosphonium­meth­yl­enetrifluoroborate

The title compound, C(19)H(17)BF(3)P {alternative name: triphen­yl[(tri­fluoro­boran­yl)meth­yl]phosphanium}, was formed by the reaction of tri­phenyl­phosphine with potassium iodo­methyl­tri­fluoro­borate. The mol­ecule features a nearly staggered conformation along the P—C bond and a less than sta...

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Autores principales: Bateman, Christopher M., Zakharov, Lev N., Abbey, Eric R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598835/
https://www.ncbi.nlm.nih.gov/pubmed/28932423
http://dx.doi.org/10.1107/S2056989017009884
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author Bateman, Christopher M.
Zakharov, Lev N.
Abbey, Eric R.
author_facet Bateman, Christopher M.
Zakharov, Lev N.
Abbey, Eric R.
author_sort Bateman, Christopher M.
collection PubMed
description The title compound, C(19)H(17)BF(3)P {alternative name: triphen­yl[(tri­fluoro­boran­yl)meth­yl]phosphanium}, was formed by the reaction of tri­phenyl­phosphine with potassium iodo­methyl­tri­fluoro­borate. The mol­ecule features a nearly staggered conformation along the P—C bond and a less than staggered conformation along the C—B bond. In the crystal, weak C—H⋯F hydrogen bonds between the meta-phenyl C—H groups and the tri­fluoro­borate B—F groups form chains of R (2) (2)(16) rings along [100]. These chains are are further stabilized by weak C—H⋯π inter­actions. A weak intra­molecular C—H⋯F hydrogen bond is also observed.
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spelling pubmed-55988352017-09-20 Crystal structure of triphenylphosphonium­meth­yl­enetrifluoroborate Bateman, Christopher M. Zakharov, Lev N. Abbey, Eric R. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(19)H(17)BF(3)P {alternative name: triphen­yl[(tri­fluoro­boran­yl)meth­yl]phosphanium}, was formed by the reaction of tri­phenyl­phosphine with potassium iodo­methyl­tri­fluoro­borate. The mol­ecule features a nearly staggered conformation along the P—C bond and a less than staggered conformation along the C—B bond. In the crystal, weak C—H⋯F hydrogen bonds between the meta-phenyl C—H groups and the tri­fluoro­borate B—F groups form chains of R (2) (2)(16) rings along [100]. These chains are are further stabilized by weak C—H⋯π inter­actions. A weak intra­molecular C—H⋯F hydrogen bond is also observed. International Union of Crystallography 2017-07-07 /pmc/articles/PMC5598835/ /pubmed/28932423 http://dx.doi.org/10.1107/S2056989017009884 Text en © Bateman et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Bateman, Christopher M.
Zakharov, Lev N.
Abbey, Eric R.
Crystal structure of triphenylphosphonium­meth­yl­enetrifluoroborate
title Crystal structure of triphenylphosphonium­meth­yl­enetrifluoroborate
title_full Crystal structure of triphenylphosphonium­meth­yl­enetrifluoroborate
title_fullStr Crystal structure of triphenylphosphonium­meth­yl­enetrifluoroborate
title_full_unstemmed Crystal structure of triphenylphosphonium­meth­yl­enetrifluoroborate
title_short Crystal structure of triphenylphosphonium­meth­yl­enetrifluoroborate
title_sort crystal structure of triphenylphosphonium­meth­yl­enetrifluoroborate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598835/
https://www.ncbi.nlm.nih.gov/pubmed/28932423
http://dx.doi.org/10.1107/S2056989017009884
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