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Crystal structure of triphenylphosphoniummethylenetrifluoroborate
The title compound, C(19)H(17)BF(3)P {alternative name: triphenyl[(trifluoroboranyl)methyl]phosphanium}, was formed by the reaction of triphenylphosphine with potassium iodomethyltrifluoroborate. The molecule features a nearly staggered conformation along the P—C bond and a less than sta...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598835/ https://www.ncbi.nlm.nih.gov/pubmed/28932423 http://dx.doi.org/10.1107/S2056989017009884 |
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author | Bateman, Christopher M. Zakharov, Lev N. Abbey, Eric R. |
author_facet | Bateman, Christopher M. Zakharov, Lev N. Abbey, Eric R. |
author_sort | Bateman, Christopher M. |
collection | PubMed |
description | The title compound, C(19)H(17)BF(3)P {alternative name: triphenyl[(trifluoroboranyl)methyl]phosphanium}, was formed by the reaction of triphenylphosphine with potassium iodomethyltrifluoroborate. The molecule features a nearly staggered conformation along the P—C bond and a less than staggered conformation along the C—B bond. In the crystal, weak C—H⋯F hydrogen bonds between the meta-phenyl C—H groups and the trifluoroborate B—F groups form chains of R (2) (2)(16) rings along [100]. These chains are are further stabilized by weak C—H⋯π interactions. A weak intramolecular C—H⋯F hydrogen bond is also observed. |
format | Online Article Text |
id | pubmed-5598835 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-55988352017-09-20 Crystal structure of triphenylphosphoniummethylenetrifluoroborate Bateman, Christopher M. Zakharov, Lev N. Abbey, Eric R. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(19)H(17)BF(3)P {alternative name: triphenyl[(trifluoroboranyl)methyl]phosphanium}, was formed by the reaction of triphenylphosphine with potassium iodomethyltrifluoroborate. The molecule features a nearly staggered conformation along the P—C bond and a less than staggered conformation along the C—B bond. In the crystal, weak C—H⋯F hydrogen bonds between the meta-phenyl C—H groups and the trifluoroborate B—F groups form chains of R (2) (2)(16) rings along [100]. These chains are are further stabilized by weak C—H⋯π interactions. A weak intramolecular C—H⋯F hydrogen bond is also observed. International Union of Crystallography 2017-07-07 /pmc/articles/PMC5598835/ /pubmed/28932423 http://dx.doi.org/10.1107/S2056989017009884 Text en © Bateman et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Bateman, Christopher M. Zakharov, Lev N. Abbey, Eric R. Crystal structure of triphenylphosphoniummethylenetrifluoroborate |
title | Crystal structure of triphenylphosphoniummethylenetrifluoroborate |
title_full | Crystal structure of triphenylphosphoniummethylenetrifluoroborate |
title_fullStr | Crystal structure of triphenylphosphoniummethylenetrifluoroborate |
title_full_unstemmed | Crystal structure of triphenylphosphoniummethylenetrifluoroborate |
title_short | Crystal structure of triphenylphosphoniummethylenetrifluoroborate |
title_sort | crystal structure of triphenylphosphoniummethylenetrifluoroborate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598835/ https://www.ncbi.nlm.nih.gov/pubmed/28932423 http://dx.doi.org/10.1107/S2056989017009884 |
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