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Crystal structure of (E)-N′-(3-fluoro-2-hydroxybenzylidene)isonicotinohydrazide
In the title compound, C(13)H(10)FN(3)O(2), the molecule has an E conformation with respect to the C=N bond of the hydrazone bridge. The dihedral angle between the isonicotinoyl and fluorophenol moieties is 4.03 (4)°, and an intramolecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598838/ https://www.ncbi.nlm.nih.gov/pubmed/28932426 http://dx.doi.org/10.1107/S2056989017009926 |
Sumario: | In the title compound, C(13)H(10)FN(3)O(2), the molecule has an E conformation with respect to the C=N bond of the hydrazone bridge. The dihedral angle between the isonicotinoyl and fluorophenol moieties is 4.03 (4)°, and an intramolecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked by N—H⋯N and C—H⋯N hydrogen bonds, forming chains propagating along the a-axis direction. The chains are linked by C—H⋯O hydrogen bonds, resulting in the formation of layers lying parallel to the ab plane. The crystal structure also features π–π interactions [centroid-to-centroid distance = 3.6887 (8) Å]. |
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