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Crystal structure of (E)-N′-(3-fluoro-2-hydroxybenzylidene)isonicotinohydrazide
In the title compound, C(13)H(10)FN(3)O(2), the molecule has an E conformation with respect to the C=N bond of the hydrazone bridge. The dihedral angle between the isonicotinoyl and fluorophenol moieties is 4.03 (4)°, and an intramolecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598838/ https://www.ncbi.nlm.nih.gov/pubmed/28932426 http://dx.doi.org/10.1107/S2056989017009926 |
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author | Jiajaroen, Suwadee Chainok, Kittipong Kielar, Filip |
author_facet | Jiajaroen, Suwadee Chainok, Kittipong Kielar, Filip |
author_sort | Jiajaroen, Suwadee |
collection | PubMed |
description | In the title compound, C(13)H(10)FN(3)O(2), the molecule has an E conformation with respect to the C=N bond of the hydrazone bridge. The dihedral angle between the isonicotinoyl and fluorophenol moieties is 4.03 (4)°, and an intramolecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked by N—H⋯N and C—H⋯N hydrogen bonds, forming chains propagating along the a-axis direction. The chains are linked by C—H⋯O hydrogen bonds, resulting in the formation of layers lying parallel to the ab plane. The crystal structure also features π–π interactions [centroid-to-centroid distance = 3.6887 (8) Å]. |
format | Online Article Text |
id | pubmed-5598838 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-55988382017-09-20 Crystal structure of (E)-N′-(3-fluoro-2-hydroxybenzylidene)isonicotinohydrazide Jiajaroen, Suwadee Chainok, Kittipong Kielar, Filip Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(13)H(10)FN(3)O(2), the molecule has an E conformation with respect to the C=N bond of the hydrazone bridge. The dihedral angle between the isonicotinoyl and fluorophenol moieties is 4.03 (4)°, and an intramolecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked by N—H⋯N and C—H⋯N hydrogen bonds, forming chains propagating along the a-axis direction. The chains are linked by C—H⋯O hydrogen bonds, resulting in the formation of layers lying parallel to the ab plane. The crystal structure also features π–π interactions [centroid-to-centroid distance = 3.6887 (8) Å]. International Union of Crystallography 2017-07-11 /pmc/articles/PMC5598838/ /pubmed/28932426 http://dx.doi.org/10.1107/S2056989017009926 Text en © Jiajaroen et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Jiajaroen, Suwadee Chainok, Kittipong Kielar, Filip Crystal structure of (E)-N′-(3-fluoro-2-hydroxybenzylidene)isonicotinohydrazide |
title | Crystal structure of (E)-N′-(3-fluoro-2-hydroxybenzylidene)isonicotinohydrazide |
title_full | Crystal structure of (E)-N′-(3-fluoro-2-hydroxybenzylidene)isonicotinohydrazide |
title_fullStr | Crystal structure of (E)-N′-(3-fluoro-2-hydroxybenzylidene)isonicotinohydrazide |
title_full_unstemmed | Crystal structure of (E)-N′-(3-fluoro-2-hydroxybenzylidene)isonicotinohydrazide |
title_short | Crystal structure of (E)-N′-(3-fluoro-2-hydroxybenzylidene)isonicotinohydrazide |
title_sort | crystal structure of (e)-n′-(3-fluoro-2-hydroxybenzylidene)isonicotinohydrazide |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598838/ https://www.ncbi.nlm.nih.gov/pubmed/28932426 http://dx.doi.org/10.1107/S2056989017009926 |
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