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Crystal structure of (E)-N′-(3-fluoro-2-hy­droxy­benzyl­idene)isonicotinohydrazide

In the title compound, C(13)H(10)FN(3)O(2), the mol­ecule has an E conformation with respect to the C=N bond of the hydrazone bridge. The dihedral angle between the isonicotinoyl and fluoro­phenol moieties is 4.03 (4)°, and an intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the...

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Autores principales: Jiajaroen, Suwadee, Chainok, Kittipong, Kielar, Filip
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598838/
https://www.ncbi.nlm.nih.gov/pubmed/28932426
http://dx.doi.org/10.1107/S2056989017009926
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author Jiajaroen, Suwadee
Chainok, Kittipong
Kielar, Filip
author_facet Jiajaroen, Suwadee
Chainok, Kittipong
Kielar, Filip
author_sort Jiajaroen, Suwadee
collection PubMed
description In the title compound, C(13)H(10)FN(3)O(2), the mol­ecule has an E conformation with respect to the C=N bond of the hydrazone bridge. The dihedral angle between the isonicotinoyl and fluoro­phenol moieties is 4.03 (4)°, and an intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked by N—H⋯N and C—H⋯N hydrogen bonds, forming chains propagating along the a-axis direction. The chains are linked by C—H⋯O hydrogen bonds, resulting in the formation of layers lying parallel to the ab plane. The crystal structure also features π–π inter­actions [centroid-to-centroid distance = 3.6887 (8) Å].
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spelling pubmed-55988382017-09-20 Crystal structure of (E)-N′-(3-fluoro-2-hy­droxy­benzyl­idene)isonicotinohydrazide Jiajaroen, Suwadee Chainok, Kittipong Kielar, Filip Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(13)H(10)FN(3)O(2), the mol­ecule has an E conformation with respect to the C=N bond of the hydrazone bridge. The dihedral angle between the isonicotinoyl and fluoro­phenol moieties is 4.03 (4)°, and an intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked by N—H⋯N and C—H⋯N hydrogen bonds, forming chains propagating along the a-axis direction. The chains are linked by C—H⋯O hydrogen bonds, resulting in the formation of layers lying parallel to the ab plane. The crystal structure also features π–π inter­actions [centroid-to-centroid distance = 3.6887 (8) Å]. International Union of Crystallography 2017-07-11 /pmc/articles/PMC5598838/ /pubmed/28932426 http://dx.doi.org/10.1107/S2056989017009926 Text en © Jiajaroen et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Jiajaroen, Suwadee
Chainok, Kittipong
Kielar, Filip
Crystal structure of (E)-N′-(3-fluoro-2-hy­droxy­benzyl­idene)isonicotinohydrazide
title Crystal structure of (E)-N′-(3-fluoro-2-hy­droxy­benzyl­idene)isonicotinohydrazide
title_full Crystal structure of (E)-N′-(3-fluoro-2-hy­droxy­benzyl­idene)isonicotinohydrazide
title_fullStr Crystal structure of (E)-N′-(3-fluoro-2-hy­droxy­benzyl­idene)isonicotinohydrazide
title_full_unstemmed Crystal structure of (E)-N′-(3-fluoro-2-hy­droxy­benzyl­idene)isonicotinohydrazide
title_short Crystal structure of (E)-N′-(3-fluoro-2-hy­droxy­benzyl­idene)isonicotinohydrazide
title_sort crystal structure of (e)-n′-(3-fluoro-2-hy­droxy­benzyl­idene)isonicotinohydrazide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598838/
https://www.ncbi.nlm.nih.gov/pubmed/28932426
http://dx.doi.org/10.1107/S2056989017009926
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