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A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(2) S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(3) S,S′:N] 4-methylpyridine hemisolvate]
The title compound, {[Zn(C(9)H(11)N(2)S(2))(2)]·0.5C(6)H(7)N}(n), comprises two independent, but chemically similar, Zn[S(2)CN(Et)CH(2)py](2) residues and a 4-methylpyridine solvent molecule in the asymmetric unit. The Zn-containing units are connected into a one-dimensional coordination polymer (...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598840/ https://www.ncbi.nlm.nih.gov/pubmed/28932428 http://dx.doi.org/10.1107/S2056989017010179 |
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author | Poplaukhin, Pavel Arman, Hadi D. Tiekink, Edward R. T. |
author_facet | Poplaukhin, Pavel Arman, Hadi D. Tiekink, Edward R. T. |
author_sort | Poplaukhin, Pavel |
collection | PubMed |
description | The title compound, {[Zn(C(9)H(11)N(2)S(2))(2)]·0.5C(6)H(7)N}(n), comprises two independent, but chemically similar, Zn[S(2)CN(Et)CH(2)py](2) residues and a 4-methylpyridine solvent molecule in the asymmetric unit. The Zn-containing units are connected into a one-dimensional coordination polymer (zigzag topology) propagating in the [010] direction, with one dithiocarbamate ligand bridging in a μ(2)-κ(3) mode, employing one pyridyl N and both dithiocarbamate S atoms, while the other is κ(2)-chelating. In each case, the resultant ZnNS(4) coordination geometry approximates a square pyramid, with the pyridyl N atom in the apical position. In the crystal, the chains are linked into a three-dimensional architecture by methyl- and pyridyl-C—H⋯S, methylene-C—H⋯N(pyridyl) and pyridyl-C—H⋯π(ZnS(2)C) interactions. The connection between the chain and the 4-methylpyridine solvent molecule is of the type pyridyl-C—H⋯N(4-methylpyridine). |
format | Online Article Text |
id | pubmed-5598840 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2017 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-55988402017-09-20 A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(2) S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(3) S,S′:N] 4-methylpyridine hemisolvate] Poplaukhin, Pavel Arman, Hadi D. Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, {[Zn(C(9)H(11)N(2)S(2))(2)]·0.5C(6)H(7)N}(n), comprises two independent, but chemically similar, Zn[S(2)CN(Et)CH(2)py](2) residues and a 4-methylpyridine solvent molecule in the asymmetric unit. The Zn-containing units are connected into a one-dimensional coordination polymer (zigzag topology) propagating in the [010] direction, with one dithiocarbamate ligand bridging in a μ(2)-κ(3) mode, employing one pyridyl N and both dithiocarbamate S atoms, while the other is κ(2)-chelating. In each case, the resultant ZnNS(4) coordination geometry approximates a square pyramid, with the pyridyl N atom in the apical position. In the crystal, the chains are linked into a three-dimensional architecture by methyl- and pyridyl-C—H⋯S, methylene-C—H⋯N(pyridyl) and pyridyl-C—H⋯π(ZnS(2)C) interactions. The connection between the chain and the 4-methylpyridine solvent molecule is of the type pyridyl-C—H⋯N(4-methylpyridine). International Union of Crystallography 2017-07-13 /pmc/articles/PMC5598840/ /pubmed/28932428 http://dx.doi.org/10.1107/S2056989017010179 Text en © Poplaukhin et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Poplaukhin, Pavel Arman, Hadi D. Tiekink, Edward R. T. A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(2) S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(3) S,S′:N] 4-methylpyridine hemisolvate] |
title | A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(2)
S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(3)
S,S′:N] 4-methylpyridine hemisolvate] |
title_full | A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(2)
S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(3)
S,S′:N] 4-methylpyridine hemisolvate] |
title_fullStr | A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(2)
S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(3)
S,S′:N] 4-methylpyridine hemisolvate] |
title_full_unstemmed | A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(2)
S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(3)
S,S′:N] 4-methylpyridine hemisolvate] |
title_short | A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(2)
S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ(3)
S,S′:N] 4-methylpyridine hemisolvate] |
title_sort | one-dimensional coordination polymer, catena-poly[[[[n-ethyl-n-(pyridin-4-ylmethyl)dithiocarbamato-κ(2)
s,s′]zinc(ii)]-μ(2)-n-ethyl-n-(pyridin-4-ylmethyl)dithiocarbamato-κ(3)
s,s′:n] 4-methylpyridine hemisolvate] |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598840/ https://www.ncbi.nlm.nih.gov/pubmed/28932428 http://dx.doi.org/10.1107/S2056989017010179 |
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