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A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(2) S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) S,S′:N] 4-methyl­pyridine hemisolvate]

The title compound, {[Zn(C(9)H(11)N(2)S(2))(2)]·0.5C(6)H(7)N}(n), comprises two independent, but chemically similar, Zn[S(2)CN(Et)CH(2)py](2) residues and a 4-methyl­pyridine solvent mol­ecule in the asymmetric unit. The Zn-containing units are connected into a one-dimensional coordination polymer (...

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Autores principales: Poplaukhin, Pavel, Arman, Hadi D., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598840/
https://www.ncbi.nlm.nih.gov/pubmed/28932428
http://dx.doi.org/10.1107/S2056989017010179
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author Poplaukhin, Pavel
Arman, Hadi D.
Tiekink, Edward R. T.
author_facet Poplaukhin, Pavel
Arman, Hadi D.
Tiekink, Edward R. T.
author_sort Poplaukhin, Pavel
collection PubMed
description The title compound, {[Zn(C(9)H(11)N(2)S(2))(2)]·0.5C(6)H(7)N}(n), comprises two independent, but chemically similar, Zn[S(2)CN(Et)CH(2)py](2) residues and a 4-methyl­pyridine solvent mol­ecule in the asymmetric unit. The Zn-containing units are connected into a one-dimensional coordination polymer (zigzag topology) propagating in the [010] direction, with one di­thio­carbamate ligand bridging in a μ(2)-κ(3) mode, employing one pyridyl N and both di­thio­carbamate S atoms, while the other is κ(2)-chelating. In each case, the resultant ZnNS(4) coordination geometry approximates a square pyramid, with the pyridyl N atom in the apical position. In the crystal, the chains are linked into a three-dimensional architecture by methyl- and pyridyl-C—H⋯S, methyl­ene-C—H⋯N(pyrid­yl) and pyridyl-C—H⋯π(ZnS(2)C) inter­actions. The connection between the chain and the 4-methyl­pyridine solvent mol­ecule is of the type pyridyl-C—H⋯N(4-methyl­pyridine).
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spelling pubmed-55988402017-09-20 A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(2) S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) S,S′:N] 4-methyl­pyridine hemisolvate] Poplaukhin, Pavel Arman, Hadi D. Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, {[Zn(C(9)H(11)N(2)S(2))(2)]·0.5C(6)H(7)N}(n), comprises two independent, but chemically similar, Zn[S(2)CN(Et)CH(2)py](2) residues and a 4-methyl­pyridine solvent mol­ecule in the asymmetric unit. The Zn-containing units are connected into a one-dimensional coordination polymer (zigzag topology) propagating in the [010] direction, with one di­thio­carbamate ligand bridging in a μ(2)-κ(3) mode, employing one pyridyl N and both di­thio­carbamate S atoms, while the other is κ(2)-chelating. In each case, the resultant ZnNS(4) coordination geometry approximates a square pyramid, with the pyridyl N atom in the apical position. In the crystal, the chains are linked into a three-dimensional architecture by methyl- and pyridyl-C—H⋯S, methyl­ene-C—H⋯N(pyrid­yl) and pyridyl-C—H⋯π(ZnS(2)C) inter­actions. The connection between the chain and the 4-methyl­pyridine solvent mol­ecule is of the type pyridyl-C—H⋯N(4-methyl­pyridine). International Union of Crystallography 2017-07-13 /pmc/articles/PMC5598840/ /pubmed/28932428 http://dx.doi.org/10.1107/S2056989017010179 Text en © Poplaukhin et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Poplaukhin, Pavel
Arman, Hadi D.
Tiekink, Edward R. T.
A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(2) S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) S,S′:N] 4-methyl­pyridine hemisolvate]
title A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(2) S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) S,S′:N] 4-methyl­pyridine hemisolvate]
title_full A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(2) S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) S,S′:N] 4-methyl­pyridine hemisolvate]
title_fullStr A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(2) S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) S,S′:N] 4-methyl­pyridine hemisolvate]
title_full_unstemmed A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(2) S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) S,S′:N] 4-methyl­pyridine hemisolvate]
title_short A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(2) S,S′]zinc(II)]-μ(2)-N-ethyl-N-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) S,S′:N] 4-methyl­pyridine hemisolvate]
title_sort one-dimensional coordination polymer, catena-poly[[[[n-ethyl-n-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(2) s,s′]zinc(ii)]-μ(2)-n-ethyl-n-(pyridin-4-ylmeth­yl)di­thio­carbamato-κ(3) s,s′:n] 4-methyl­pyridine hemisolvate]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598840/
https://www.ncbi.nlm.nih.gov/pubmed/28932428
http://dx.doi.org/10.1107/S2056989017010179
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