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Crystal structure of 2-tert-butyl-2,3-dihydro-1H-benzo[c]pyrrol-1-one
The asymmetric unit of the title compound, C(12)H(15)NO, comprises two symmetry-independent molecules which differ mainly in the conformations of the tert-butyl groups. The molecules contain an essentially planar five-membered 3-pyrroline ring incorporating a carbonyl substituent (pyrrolinone) wh...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598845/ https://www.ncbi.nlm.nih.gov/pubmed/28932433 http://dx.doi.org/10.1107/S2056989017010337 |
Sumario: | The asymmetric unit of the title compound, C(12)H(15)NO, comprises two symmetry-independent molecules which differ mainly in the conformations of the tert-butyl groups. The molecules contain an essentially planar five-membered 3-pyrroline ring incorporating a carbonyl substituent (pyrrolinone) which forms part of an isoindolinone skeleton. The planarity of the pyrrole ring is compared to other structures with isoindolinone. There are only weak intra- and intermolecular C—H⋯O and C—H⋯π-electron-ring interactions in the crystal structure. |
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