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Crystal structure of 2-tert-butyl-2,3-di­hydro-1H-benzo[c]pyrrol-1-one

The asymmetric unit of the title compound, C(12)H(15)NO, comprises two sym­metry-independent mol­ecules which differ mainly in the conformations of the tert-butyl groups. The mol­ecules contain an essentially planar five-membered 3-pyrroline ring incorporating a carbonyl substituent (pyrrolinone) wh...

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Detalles Bibliográficos
Autores principales: Donkeng Dazie, Joel, Ludvík, Jiří, Fábry, Jan, Eigner, Václav
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598845/
https://www.ncbi.nlm.nih.gov/pubmed/28932433
http://dx.doi.org/10.1107/S2056989017010337
Descripción
Sumario:The asymmetric unit of the title compound, C(12)H(15)NO, comprises two sym­metry-independent mol­ecules which differ mainly in the conformations of the tert-butyl groups. The mol­ecules contain an essentially planar five-membered 3-pyrroline ring incorporating a carbonyl substituent (pyrrolinone) which forms part of an isoindolinone skeleton. The planarity of the pyrrole ring is compared to other structures with isoindolinone. There are only weak intra- and inter­molecular C—H⋯O and C—H⋯π-electron-ring inter­actions in the crystal structure.