Crystallographic and spectroscopic characterization of 5-chloro­pyridine-2,3-di­amine

The two ortho-amino groups of the title compound, C(5)H(6)ClN(3), twist out of the plane of the mol­ecule to minimize intra­molecular inter­action between the amino hydrogen atoms. In the crystal, the amino groups and the pyridine N atom engage in inter­molecular hydrogen bonding. The mol­ecules pac...

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Detalles Bibliográficos
Autores principales: Sulovari, Aron, Tanski, Joseph M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598851/
https://www.ncbi.nlm.nih.gov/pubmed/28932439
http://dx.doi.org/10.1107/S2056989017010489
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author Sulovari, Aron
Tanski, Joseph M.
author_facet Sulovari, Aron
Tanski, Joseph M.
author_sort Sulovari, Aron
collection PubMed
description The two ortho-amino groups of the title compound, C(5)H(6)ClN(3), twist out of the plane of the mol­ecule to minimize intra­molecular inter­action between the amino hydrogen atoms. In the crystal, the amino groups and the pyridine N atom engage in inter­molecular hydrogen bonding. The mol­ecules pack into spiral hydrogen-bonded columns with offset face-to-face π-stacking.
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spelling pubmed-55988512017-09-20 Crystallographic and spectroscopic characterization of 5-chloro­pyridine-2,3-di­amine Sulovari, Aron Tanski, Joseph M. Acta Crystallogr E Crystallogr Commun Research Communications The two ortho-amino groups of the title compound, C(5)H(6)ClN(3), twist out of the plane of the mol­ecule to minimize intra­molecular inter­action between the amino hydrogen atoms. In the crystal, the amino groups and the pyridine N atom engage in inter­molecular hydrogen bonding. The mol­ecules pack into spiral hydrogen-bonded columns with offset face-to-face π-stacking. International Union of Crystallography 2017-07-21 /pmc/articles/PMC5598851/ /pubmed/28932439 http://dx.doi.org/10.1107/S2056989017010489 Text en © Sulovari and Tanski 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Sulovari, Aron
Tanski, Joseph M.
Crystallographic and spectroscopic characterization of 5-chloro­pyridine-2,3-di­amine
title Crystallographic and spectroscopic characterization of 5-chloro­pyridine-2,3-di­amine
title_full Crystallographic and spectroscopic characterization of 5-chloro­pyridine-2,3-di­amine
title_fullStr Crystallographic and spectroscopic characterization of 5-chloro­pyridine-2,3-di­amine
title_full_unstemmed Crystallographic and spectroscopic characterization of 5-chloro­pyridine-2,3-di­amine
title_short Crystallographic and spectroscopic characterization of 5-chloro­pyridine-2,3-di­amine
title_sort crystallographic and spectroscopic characterization of 5-chloro­pyridine-2,3-di­amine
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598851/
https://www.ncbi.nlm.nih.gov/pubmed/28932439
http://dx.doi.org/10.1107/S2056989017010489
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