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Crystal structures of three 1-[4-(4-bromobutoxy)phenyl] chalcone derivatives: (E)-1-[4-(4-bromobutoxy)phenyl]-3-phenylprop-2-en-1-one, (E)-1-[4-(4-bromobutoxy)phenyl]-3-(4-methoxyphenyl)prop-2-en-1-one and (E)-1-[4-(4-bromobutoxy)phenyl]-3-(3,4-dimethoxyphenyl)prop-2-en-1-one
The crystal structures of three chalcones with a bromo-substituted butoxy side chain, viz. (E)-1-[4-(4-bromobutoxy)phenyl]-3-phenylprop-2-en-1-one, C(19)H(19)BrO(2), (I), (E)-1-[4-(4-bromobutoxy)phenyl]-3-(4-methoxyphenyl)prop-2-en-1-one, C(20)H(21)BrO(3), (II), and (E)-1-[4-(4-bromobu...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598855/ https://www.ncbi.nlm.nih.gov/pubmed/28932443 http://dx.doi.org/10.1107/S2056989017010052 |
Sumario: | The crystal structures of three chalcones with a bromo-substituted butoxy side chain, viz. (E)-1-[4-(4-bromobutoxy)phenyl]-3-phenylprop-2-en-1-one, C(19)H(19)BrO(2), (I), (E)-1-[4-(4-bromobutoxy)phenyl]-3-(4-methoxyphenyl)prop-2-en-1-one, C(20)H(21)BrO(3), (II), and (E)-1-[4-(4-bromobutoxy)phenyl]-3-(3,4-dimethoxyphenyl)prop-2-en-1-one, C(21)H(23)BrO(4), (III), are reported. In all molecules, the conformation of the keto group with respect to the olefinic bond is s-cis. Molecules of (I) and (II) are nearly planar, while molecule (III) is not planar. In the crystal of compounds (I) and (II), molecules are linked into chains parallel to the c axis by C—H⋯π interactions. In the crystal of compound (III), molecules are linked by a pairs of C—H⋯O hydrogen bonds, forming inversion dimers. Weak C—Br⋯π interactions are also observed in (III). |
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