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Crystal structures of three 1-[4-(4-bromo­but­oxy)­phen­yl] chalcone derivatives: (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-phenyl­prop-2-en-1-one, (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(4-meth­oxy­phen­yl)prop-2-en-1-one and (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one

The crystal structures of three chalcones with a bromo-substituted but­oxy side chain, viz. (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-phenyl­prop-2-en-1-one, C(19)H(19)BrO(2), (I), (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(4-meth­oxy­phen­yl)prop-2-en-1-one, C(20)H(21)BrO(3), (II), and (E)-1-[4-(4-bromo­bu...

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Autores principales: Maragatham, Gunasekaran, Selvarani, Sivasamy, Rajakumar, Perumal, Lakshmi, Srinivasakannan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598855/
https://www.ncbi.nlm.nih.gov/pubmed/28932443
http://dx.doi.org/10.1107/S2056989017010052
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author Maragatham, Gunasekaran
Selvarani, Sivasamy
Rajakumar, Perumal
Lakshmi, Srinivasakannan
author_facet Maragatham, Gunasekaran
Selvarani, Sivasamy
Rajakumar, Perumal
Lakshmi, Srinivasakannan
author_sort Maragatham, Gunasekaran
collection PubMed
description The crystal structures of three chalcones with a bromo-substituted but­oxy side chain, viz. (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-phenyl­prop-2-en-1-one, C(19)H(19)BrO(2), (I), (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(4-meth­oxy­phen­yl)prop-2-en-1-one, C(20)H(21)BrO(3), (II), and (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one, C(21)H(23)BrO(4), (III), are reported. In all mol­ecules, the conformation of the keto group with respect to the olefinic bond is s-cis. Mol­ecules of (I) and (II) are nearly planar, while mol­ecule (III) is not planar. In the crystal of compounds (I) and (II), mol­ecules are linked into chains parallel to the c axis by C—H⋯π inter­actions. In the crystal of compound (III), mol­ecules are linked by a pairs of C—H⋯O hydrogen bonds, forming inversion dimers. Weak C—Br⋯π inter­actions are also observed in (III).
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spelling pubmed-55988552017-09-20 Crystal structures of three 1-[4-(4-bromo­but­oxy)­phen­yl] chalcone derivatives: (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-phenyl­prop-2-en-1-one, (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(4-meth­oxy­phen­yl)prop-2-en-1-one and (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one Maragatham, Gunasekaran Selvarani, Sivasamy Rajakumar, Perumal Lakshmi, Srinivasakannan Acta Crystallogr E Crystallogr Commun Research Communications The crystal structures of three chalcones with a bromo-substituted but­oxy side chain, viz. (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-phenyl­prop-2-en-1-one, C(19)H(19)BrO(2), (I), (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(4-meth­oxy­phen­yl)prop-2-en-1-one, C(20)H(21)BrO(3), (II), and (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one, C(21)H(23)BrO(4), (III), are reported. In all mol­ecules, the conformation of the keto group with respect to the olefinic bond is s-cis. Mol­ecules of (I) and (II) are nearly planar, while mol­ecule (III) is not planar. In the crystal of compounds (I) and (II), mol­ecules are linked into chains parallel to the c axis by C—H⋯π inter­actions. In the crystal of compound (III), mol­ecules are linked by a pairs of C—H⋯O hydrogen bonds, forming inversion dimers. Weak C—Br⋯π inter­actions are also observed in (III). International Union of Crystallography 2017-07-21 /pmc/articles/PMC5598855/ /pubmed/28932443 http://dx.doi.org/10.1107/S2056989017010052 Text en © Maragatham et al. 2017 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Maragatham, Gunasekaran
Selvarani, Sivasamy
Rajakumar, Perumal
Lakshmi, Srinivasakannan
Crystal structures of three 1-[4-(4-bromo­but­oxy)­phen­yl] chalcone derivatives: (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-phenyl­prop-2-en-1-one, (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(4-meth­oxy­phen­yl)prop-2-en-1-one and (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one
title Crystal structures of three 1-[4-(4-bromo­but­oxy)­phen­yl] chalcone derivatives: (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-phenyl­prop-2-en-1-one, (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(4-meth­oxy­phen­yl)prop-2-en-1-one and (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one
title_full Crystal structures of three 1-[4-(4-bromo­but­oxy)­phen­yl] chalcone derivatives: (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-phenyl­prop-2-en-1-one, (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(4-meth­oxy­phen­yl)prop-2-en-1-one and (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one
title_fullStr Crystal structures of three 1-[4-(4-bromo­but­oxy)­phen­yl] chalcone derivatives: (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-phenyl­prop-2-en-1-one, (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(4-meth­oxy­phen­yl)prop-2-en-1-one and (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one
title_full_unstemmed Crystal structures of three 1-[4-(4-bromo­but­oxy)­phen­yl] chalcone derivatives: (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-phenyl­prop-2-en-1-one, (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(4-meth­oxy­phen­yl)prop-2-en-1-one and (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one
title_short Crystal structures of three 1-[4-(4-bromo­but­oxy)­phen­yl] chalcone derivatives: (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-phenyl­prop-2-en-1-one, (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(4-meth­oxy­phen­yl)prop-2-en-1-one and (E)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one
title_sort crystal structures of three 1-[4-(4-bromo­but­oxy)­phen­yl] chalcone derivatives: (e)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-phenyl­prop-2-en-1-one, (e)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(4-meth­oxy­phen­yl)prop-2-en-1-one and (e)-1-[4-(4-bromo­but­oxy)­phen­yl]-3-(3,4-di­meth­oxy­phen­yl)prop-2-en-1-one
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5598855/
https://www.ncbi.nlm.nih.gov/pubmed/28932443
http://dx.doi.org/10.1107/S2056989017010052
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