Synthesis of flower-like magnetite nanoassembly: Application in the efficient reduction of nitroarenes

A facile approach for the synthesis of magnetite microspheres with flower-like morphology is reported that proceeds via the reduction of iron(III) oxide under a hydrogen atmosphere. The ensuing magnetic catalyst is well characterized by XRD, FE-SEM, TEM, N(2) adsorption-desorption isotherm, and Möss...

Descripción completa

Detalles Bibliográficos
Autores principales: Datta, Kasibhatta J., Rathi, Anuj K., Kumar, Pawan, Kaslik, Josef, Medrik, Ivo, Ranc, Vaclav, Varma, Rajender S., Zboril, Radek, Gawande, Manoj B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5599566/
https://www.ncbi.nlm.nih.gov/pubmed/28912493
http://dx.doi.org/10.1038/s41598-017-09477-7
_version_ 1783264083580026880
author Datta, Kasibhatta J.
Rathi, Anuj K.
Kumar, Pawan
Kaslik, Josef
Medrik, Ivo
Ranc, Vaclav
Varma, Rajender S.
Zboril, Radek
Gawande, Manoj B.
author_facet Datta, Kasibhatta J.
Rathi, Anuj K.
Kumar, Pawan
Kaslik, Josef
Medrik, Ivo
Ranc, Vaclav
Varma, Rajender S.
Zboril, Radek
Gawande, Manoj B.
author_sort Datta, Kasibhatta J.
collection PubMed
description A facile approach for the synthesis of magnetite microspheres with flower-like morphology is reported that proceeds via the reduction of iron(III) oxide under a hydrogen atmosphere. The ensuing magnetic catalyst is well characterized by XRD, FE-SEM, TEM, N(2) adsorption-desorption isotherm, and Mössbauer spectroscopy and explored for a simple yet efficient transfer hydrogenation reduction of a variety of nitroarenes to respective anilines in good to excellent yields (up to 98%) employing hydrazine hydrate. The catalyst could be easily separated at the end of a reaction using an external magnet and can be recycled up to 10 times without any loss in catalytic activity.
format Online
Article
Text
id pubmed-5599566
institution National Center for Biotechnology Information
language English
publishDate 2017
publisher Nature Publishing Group UK
record_format MEDLINE/PubMed
spelling pubmed-55995662017-09-15 Synthesis of flower-like magnetite nanoassembly: Application in the efficient reduction of nitroarenes Datta, Kasibhatta J. Rathi, Anuj K. Kumar, Pawan Kaslik, Josef Medrik, Ivo Ranc, Vaclav Varma, Rajender S. Zboril, Radek Gawande, Manoj B. Sci Rep Article A facile approach for the synthesis of magnetite microspheres with flower-like morphology is reported that proceeds via the reduction of iron(III) oxide under a hydrogen atmosphere. The ensuing magnetic catalyst is well characterized by XRD, FE-SEM, TEM, N(2) adsorption-desorption isotherm, and Mössbauer spectroscopy and explored for a simple yet efficient transfer hydrogenation reduction of a variety of nitroarenes to respective anilines in good to excellent yields (up to 98%) employing hydrazine hydrate. The catalyst could be easily separated at the end of a reaction using an external magnet and can be recycled up to 10 times without any loss in catalytic activity. Nature Publishing Group UK 2017-09-14 /pmc/articles/PMC5599566/ /pubmed/28912493 http://dx.doi.org/10.1038/s41598-017-09477-7 Text en © The Author(s) 2017 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Datta, Kasibhatta J.
Rathi, Anuj K.
Kumar, Pawan
Kaslik, Josef
Medrik, Ivo
Ranc, Vaclav
Varma, Rajender S.
Zboril, Radek
Gawande, Manoj B.
Synthesis of flower-like magnetite nanoassembly: Application in the efficient reduction of nitroarenes
title Synthesis of flower-like magnetite nanoassembly: Application in the efficient reduction of nitroarenes
title_full Synthesis of flower-like magnetite nanoassembly: Application in the efficient reduction of nitroarenes
title_fullStr Synthesis of flower-like magnetite nanoassembly: Application in the efficient reduction of nitroarenes
title_full_unstemmed Synthesis of flower-like magnetite nanoassembly: Application in the efficient reduction of nitroarenes
title_short Synthesis of flower-like magnetite nanoassembly: Application in the efficient reduction of nitroarenes
title_sort synthesis of flower-like magnetite nanoassembly: application in the efficient reduction of nitroarenes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5599566/
https://www.ncbi.nlm.nih.gov/pubmed/28912493
http://dx.doi.org/10.1038/s41598-017-09477-7
work_keys_str_mv AT dattakasibhattaj synthesisofflowerlikemagnetitenanoassemblyapplicationintheefficientreductionofnitroarenes
AT rathianujk synthesisofflowerlikemagnetitenanoassemblyapplicationintheefficientreductionofnitroarenes
AT kumarpawan synthesisofflowerlikemagnetitenanoassemblyapplicationintheefficientreductionofnitroarenes
AT kaslikjosef synthesisofflowerlikemagnetitenanoassemblyapplicationintheefficientreductionofnitroarenes
AT medrikivo synthesisofflowerlikemagnetitenanoassemblyapplicationintheefficientreductionofnitroarenes
AT rancvaclav synthesisofflowerlikemagnetitenanoassemblyapplicationintheefficientreductionofnitroarenes
AT varmarajenders synthesisofflowerlikemagnetitenanoassemblyapplicationintheefficientreductionofnitroarenes
AT zborilradek synthesisofflowerlikemagnetitenanoassemblyapplicationintheefficientreductionofnitroarenes
AT gawandemanojb synthesisofflowerlikemagnetitenanoassemblyapplicationintheefficientreductionofnitroarenes

Ejemplares similares