Harnessing polarisation transfer to indazole and imidazole through signal amplification by reversible exchange to improve their NMR detectability

The signal amplification by reversible exchange (SABRE) approach has been used to hyperpolarise the substrates indazole and imidazole in the presence of the co‐ligand acetonitrile through the action of the precataysts [IrCl(COD)(IMes)] and [IrCl(COD)(SIMes)]. (2)H‐labelled forms of these catalysts w...

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Detalles Bibliográficos
Autores principales: Fekete, Marianna, Rayner, Peter J., Green, Gary G. R., Duckett, Simon B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5599957/
https://www.ncbi.nlm.nih.gov/pubmed/28497481
http://dx.doi.org/10.1002/mrc.4607

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5599957/
https://www.ncbi.nlm.nih.gov/pubmed/28497481
http://dx.doi.org/10.1002/mrc.4607

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