Carbon dioxide binary crystals via the thermal decomposition of RDX at high pressure

A carbon dioxide and nitrous oxide solid solution has been captured in a diamond anvil cell following the thermal decomposition of 1,3,5-trinitroperhydro-1,3,5-triazine (RDX) at high temperatures and pressures. This is the first time a carbon dioxide binary solid has been observed at high pressure....

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Autores principales: Connor, L. E., Morrison, C. A., Oswald, I. D. H., Pulham, C. R., Warren, M. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5603901/
https://www.ncbi.nlm.nih.gov/pubmed/28959411
http://dx.doi.org/10.1039/c7sc01379e
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author Connor, L. E.
Morrison, C. A.
Oswald, I. D. H.
Pulham, C. R.
Warren, M. R.
author_facet Connor, L. E.
Morrison, C. A.
Oswald, I. D. H.
Pulham, C. R.
Warren, M. R.
author_sort Connor, L. E.
collection PubMed
description A carbon dioxide and nitrous oxide solid solution has been captured in a diamond anvil cell following the thermal decomposition of 1,3,5-trinitroperhydro-1,3,5-triazine (RDX) at high temperatures and pressures. This is the first time a carbon dioxide binary solid has been observed at high pressure. This observation has stimulated low temperature crystallographic studies of this binary system using recently developed gas absorption apparatus and computational modelling.
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spelling pubmed-56039012017-09-28 Carbon dioxide binary crystals via the thermal decomposition of RDX at high pressure Connor, L. E. Morrison, C. A. Oswald, I. D. H. Pulham, C. R. Warren, M. R. Chem Sci Chemistry A carbon dioxide and nitrous oxide solid solution has been captured in a diamond anvil cell following the thermal decomposition of 1,3,5-trinitroperhydro-1,3,5-triazine (RDX) at high temperatures and pressures. This is the first time a carbon dioxide binary solid has been observed at high pressure. This observation has stimulated low temperature crystallographic studies of this binary system using recently developed gas absorption apparatus and computational modelling. Royal Society of Chemistry 2017-07-01 2017-05-04 /pmc/articles/PMC5603901/ /pubmed/28959411 http://dx.doi.org/10.1039/c7sc01379e Text en This journal is © The Royal Society of Chemistry 2017 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Connor, L. E.
Morrison, C. A.
Oswald, I. D. H.
Pulham, C. R.
Warren, M. R.
Carbon dioxide binary crystals via the thermal decomposition of RDX at high pressure
title Carbon dioxide binary crystals via the thermal decomposition of RDX at high pressure
title_full Carbon dioxide binary crystals via the thermal decomposition of RDX at high pressure
title_fullStr Carbon dioxide binary crystals via the thermal decomposition of RDX at high pressure
title_full_unstemmed Carbon dioxide binary crystals via the thermal decomposition of RDX at high pressure
title_short Carbon dioxide binary crystals via the thermal decomposition of RDX at high pressure
title_sort carbon dioxide binary crystals via the thermal decomposition of rdx at high pressure
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5603901/
https://www.ncbi.nlm.nih.gov/pubmed/28959411
http://dx.doi.org/10.1039/c7sc01379e
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