Dialing in single-site reactivity of a supported calixarene-protected tetrairidium cluster catalyst

A closed Ir(4) carbonyl cluster, 1, comprising a tetrahedral metal frame and three sterically bulky tert-butyl-calix[4]arene(OPr)(3)(OCH(2)PPh(2)) (Ph = phenyl; Pr = propyl) ligands at the basal plane, was characterized with variable-temperature (13)C NMR spectroscopy, which show the absence of scra...

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Detalles Bibliográficos
Autores principales: Palermo, Andrew, Solovyov, Andrew, Ertler, Daniel, Okrut, Alexander, Gates, Bruce C., Katz, Alexander
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5607854/
https://www.ncbi.nlm.nih.gov/pubmed/28959418
http://dx.doi.org/10.1039/c7sc00686a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5607854/
https://www.ncbi.nlm.nih.gov/pubmed/28959418
http://dx.doi.org/10.1039/c7sc00686a

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