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Dialing in single-site reactivity of a supported calixarene-protected tetrairidium cluster catalyst
A closed Ir(4) carbonyl cluster, 1, comprising a tetrahedral metal frame and three sterically bulky tert-butyl-calix[4]arene(OPr)(3)(OCH(2)PPh(2)) (Ph = phenyl; Pr = propyl) ligands at the basal plane, was characterized with variable-temperature (13)C NMR spectroscopy, which show the absence of scra...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5607854/ https://www.ncbi.nlm.nih.gov/pubmed/28959418 http://dx.doi.org/10.1039/c7sc00686a |