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Single crystal structures and theoretical calculations of uranium endohedral metallofullerenes (U@C(2n), 2n = 74, 82) show cage isomer dependent oxidation states for U
Charge transfer is a general phenomenon observed for all endohedral mono-metallofullerenes. Since the detection of the first endohedral metallofullerene (EMF), La@C(82), in 1991, it has always been observed that the oxidation state of a given encapsulated metal is always the same, regardless of the...
Autores principales: | , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5607891/ https://www.ncbi.nlm.nih.gov/pubmed/28970908 http://dx.doi.org/10.1039/c7sc01711a |