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Single crystal structures and theoretical calculations of uranium endohedral metallofullerenes (U@C(2n), 2n = 74, 82) show cage isomer dependent oxidation states for U

Charge transfer is a general phenomenon observed for all endohedral mono-metallofullerenes. Since the detection of the first endohedral metallofullerene (EMF), La@C(82), in 1991, it has always been observed that the oxidation state of a given encapsulated metal is always the same, regardless of the...

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Detalles Bibliográficos
Autores principales: Cai, Wenting, Morales-Martínez, Roser, Zhang, Xingxing, Najera, Daniel, Romero, Elkin L., Metta-Magaña, Alejandro, Rodríguez-Fortea, Antonio, Fortier, Skye, Chen, Ning, Poblet, Josep M., Echegoyen, Luis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5607891/
https://www.ncbi.nlm.nih.gov/pubmed/28970908
http://dx.doi.org/10.1039/c7sc01711a