Chemical reaction within a compact non-porous crystal containing molecular clusters without the loss of crystallinity

The very rare occurrence of a gas–solid chemical reaction has been found to take place on a molecule within a compact non-porous crystal without destroying its long-range structural order and retaining similar crystal structures when yellow crystals of FeII4(mbm)(4)Cl(4)(MeOH)(4) were exposed to air...

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Autores principales: Zhang, Ming, Yang, Tao, Wang, Zhenxing, Ma, Xiong-Feng, Zhang, Yuexing, Greer, Samuel M., Stoian, Sebastian A., Ouyang, Zhong-Wen, Nojiri, Hiroyuki, Kurmoo, Mohamedally, Zeng, Ming-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5609145/
https://www.ncbi.nlm.nih.gov/pubmed/28970914
http://dx.doi.org/10.1039/c7sc01041a
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author Zhang, Ming
Yang, Tao
Wang, Zhenxing
Ma, Xiong-Feng
Zhang, Yuexing
Greer, Samuel M.
Stoian, Sebastian A.
Ouyang, Zhong-Wen
Nojiri, Hiroyuki
Kurmoo, Mohamedally
Zeng, Ming-Hua
author_facet Zhang, Ming
Yang, Tao
Wang, Zhenxing
Ma, Xiong-Feng
Zhang, Yuexing
Greer, Samuel M.
Stoian, Sebastian A.
Ouyang, Zhong-Wen
Nojiri, Hiroyuki
Kurmoo, Mohamedally
Zeng, Ming-Hua
author_sort Zhang, Ming
collection PubMed
description The very rare occurrence of a gas–solid chemical reaction has been found to take place on a molecule within a compact non-porous crystal without destroying its long-range structural order and retaining similar crystal structures when yellow crystals of FeII4(mbm)(4)Cl(4)(MeOH)(4) were exposed to air to give black [FeIII4(mbm)(4)Cl(4)(OH)(4)]·2H(2)O. The latter cannot be synthesised directly. The original cluster underwent an exchange of methanol to hydroxide, an oxidation of Fe(ii) to Fe(iii), a change in stereochemistry and hydration while the packing and space-group remained unaltered.
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spelling pubmed-56091452017-10-02 Chemical reaction within a compact non-porous crystal containing molecular clusters without the loss of crystallinity Zhang, Ming Yang, Tao Wang, Zhenxing Ma, Xiong-Feng Zhang, Yuexing Greer, Samuel M. Stoian, Sebastian A. Ouyang, Zhong-Wen Nojiri, Hiroyuki Kurmoo, Mohamedally Zeng, Ming-Hua Chem Sci Chemistry The very rare occurrence of a gas–solid chemical reaction has been found to take place on a molecule within a compact non-porous crystal without destroying its long-range structural order and retaining similar crystal structures when yellow crystals of FeII4(mbm)(4)Cl(4)(MeOH)(4) were exposed to air to give black [FeIII4(mbm)(4)Cl(4)(OH)(4)]·2H(2)O. The latter cannot be synthesised directly. The original cluster underwent an exchange of methanol to hydroxide, an oxidation of Fe(ii) to Fe(iii), a change in stereochemistry and hydration while the packing and space-group remained unaltered. Royal Society of Chemistry 2017-08-01 2017-06-19 /pmc/articles/PMC5609145/ /pubmed/28970914 http://dx.doi.org/10.1039/c7sc01041a Text en This journal is © The Royal Society of Chemistry 2017 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Zhang, Ming
Yang, Tao
Wang, Zhenxing
Ma, Xiong-Feng
Zhang, Yuexing
Greer, Samuel M.
Stoian, Sebastian A.
Ouyang, Zhong-Wen
Nojiri, Hiroyuki
Kurmoo, Mohamedally
Zeng, Ming-Hua
Chemical reaction within a compact non-porous crystal containing molecular clusters without the loss of crystallinity
title Chemical reaction within a compact non-porous crystal containing molecular clusters without the loss of crystallinity
title_full Chemical reaction within a compact non-porous crystal containing molecular clusters without the loss of crystallinity
title_fullStr Chemical reaction within a compact non-porous crystal containing molecular clusters without the loss of crystallinity
title_full_unstemmed Chemical reaction within a compact non-porous crystal containing molecular clusters without the loss of crystallinity
title_short Chemical reaction within a compact non-porous crystal containing molecular clusters without the loss of crystallinity
title_sort chemical reaction within a compact non-porous crystal containing molecular clusters without the loss of crystallinity
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5609145/
https://www.ncbi.nlm.nih.gov/pubmed/28970914
http://dx.doi.org/10.1039/c7sc01041a
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