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Rapid reversible borane to boryl hydride exchange by metal shuttling on the carborane cluster surface
In this work, we introduce a novel concept of a borane group vicinal to a metal boryl bond acting as a supporting hemilabile ligand in exohedrally metalated three-dimensional carborane clusters. The (POBOP)Ru(Cl)(PPh(3)) pincer complex (POBOP = 1,7-OP(i-Pr)(2)-m-2-carboranyl) features extreme distor...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5609532/ https://www.ncbi.nlm.nih.gov/pubmed/28970919 http://dx.doi.org/10.1039/c7sc01846k |