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Fabrication of 3-methoxyphenol sensor based on Fe(3)O(4) decorated carbon nanotube nanocomposites for environmental safety: Real sample analyses
Iron oxide ornamented carbon nanotube nanocomposites (Fe(3)O(4).CNT NCs) were prepared by a wet-chemical process in basic means. The optical, morphological, and structural characterizations of Fe(3)O(4).CNT NCs were performed using FTIR, UV/Vis., FESEM, TEM; XEDS, XPS, and XRD respectively. Flat GCE...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Public Library of Science
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5609863/ https://www.ncbi.nlm.nih.gov/pubmed/28938019 http://dx.doi.org/10.1371/journal.pone.0177817 |
Sumario: | Iron oxide ornamented carbon nanotube nanocomposites (Fe(3)O(4).CNT NCs) were prepared by a wet-chemical process in basic means. The optical, morphological, and structural characterizations of Fe(3)O(4).CNT NCs were performed using FTIR, UV/Vis., FESEM, TEM; XEDS, XPS, and XRD respectively. Flat GCE had been fabricated with a thin-layer of NCs using a coating binding agent. It was performed for the chemical sensor development by a dependable I-V technique. Among all interfering analytes, 3-methoxyphenol (3-MP) was selective towards the fabricated sensor. Increased electrochemical performances for example elevated sensitivity, linear dynamic range (LDR) and continuing steadiness towards selective 3-MP had been observed with chemical sensor. The calibration graph found linear (R(2) = 0.9340) in a wide range of 3-MP concentration (90.0 pM ~ 90.0 mM). The limit of detection and sensitivity were considered as 1.0 pM and 9×10(−4) μAμM(-1)cm(-2) respectively. The prepared of Fe(3)O(4).CNT NCs by a wet-chemical progression is an interesting route for the development of hazardous phenolic sensor based on nanocomposite materials. It is also recommended that 3-MP sensor is exhibited a promising performances based on Fe(3)O(4).CNT NCs by a facile I-V method for the significant applications of toxic chemicals for the safety of environmental and health-care fields. |
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