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Fabrication of 3-methoxyphenol sensor based on Fe(3)O(4) decorated carbon nanotube nanocomposites for environmental safety: Real sample analyses

Iron oxide ornamented carbon nanotube nanocomposites (Fe(3)O(4).CNT NCs) were prepared by a wet-chemical process in basic means. The optical, morphological, and structural characterizations of Fe(3)O(4).CNT NCs were performed using FTIR, UV/Vis., FESEM, TEM; XEDS, XPS, and XRD respectively. Flat GCE...

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Detalles Bibliográficos
Autores principales: Rahman, Mohammed M., Hussain, Mohammad Musarraf, Asiri, Abdullah M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Public Library of Science 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5609863/
https://www.ncbi.nlm.nih.gov/pubmed/28938019
http://dx.doi.org/10.1371/journal.pone.0177817
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author Rahman, Mohammed M.
Hussain, Mohammad Musarraf
Asiri, Abdullah M.
author_facet Rahman, Mohammed M.
Hussain, Mohammad Musarraf
Asiri, Abdullah M.
author_sort Rahman, Mohammed M.
collection PubMed
description Iron oxide ornamented carbon nanotube nanocomposites (Fe(3)O(4).CNT NCs) were prepared by a wet-chemical process in basic means. The optical, morphological, and structural characterizations of Fe(3)O(4).CNT NCs were performed using FTIR, UV/Vis., FESEM, TEM; XEDS, XPS, and XRD respectively. Flat GCE had been fabricated with a thin-layer of NCs using a coating binding agent. It was performed for the chemical sensor development by a dependable I-V technique. Among all interfering analytes, 3-methoxyphenol (3-MP) was selective towards the fabricated sensor. Increased electrochemical performances for example elevated sensitivity, linear dynamic range (LDR) and continuing steadiness towards selective 3-MP had been observed with chemical sensor. The calibration graph found linear (R(2) = 0.9340) in a wide range of 3-MP concentration (90.0 pM ~ 90.0 mM). The limit of detection and sensitivity were considered as 1.0 pM and 9×10(−4) μAμM(-1)cm(-2) respectively. The prepared of Fe(3)O(4).CNT NCs by a wet-chemical progression is an interesting route for the development of hazardous phenolic sensor based on nanocomposite materials. It is also recommended that 3-MP sensor is exhibited a promising performances based on Fe(3)O(4).CNT NCs by a facile I-V method for the significant applications of toxic chemicals for the safety of environmental and health-care fields.
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spelling pubmed-56098632017-10-17 Fabrication of 3-methoxyphenol sensor based on Fe(3)O(4) decorated carbon nanotube nanocomposites for environmental safety: Real sample analyses Rahman, Mohammed M. Hussain, Mohammad Musarraf Asiri, Abdullah M. PLoS One Research Article Iron oxide ornamented carbon nanotube nanocomposites (Fe(3)O(4).CNT NCs) were prepared by a wet-chemical process in basic means. The optical, morphological, and structural characterizations of Fe(3)O(4).CNT NCs were performed using FTIR, UV/Vis., FESEM, TEM; XEDS, XPS, and XRD respectively. Flat GCE had been fabricated with a thin-layer of NCs using a coating binding agent. It was performed for the chemical sensor development by a dependable I-V technique. Among all interfering analytes, 3-methoxyphenol (3-MP) was selective towards the fabricated sensor. Increased electrochemical performances for example elevated sensitivity, linear dynamic range (LDR) and continuing steadiness towards selective 3-MP had been observed with chemical sensor. The calibration graph found linear (R(2) = 0.9340) in a wide range of 3-MP concentration (90.0 pM ~ 90.0 mM). The limit of detection and sensitivity were considered as 1.0 pM and 9×10(−4) μAμM(-1)cm(-2) respectively. The prepared of Fe(3)O(4).CNT NCs by a wet-chemical progression is an interesting route for the development of hazardous phenolic sensor based on nanocomposite materials. It is also recommended that 3-MP sensor is exhibited a promising performances based on Fe(3)O(4).CNT NCs by a facile I-V method for the significant applications of toxic chemicals for the safety of environmental and health-care fields. Public Library of Science 2017-09-22 /pmc/articles/PMC5609863/ /pubmed/28938019 http://dx.doi.org/10.1371/journal.pone.0177817 Text en © 2017 Rahman et al http://creativecommons.org/licenses/by/4.0/ This is an open access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/) , which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
spellingShingle Research Article
Rahman, Mohammed M.
Hussain, Mohammad Musarraf
Asiri, Abdullah M.
Fabrication of 3-methoxyphenol sensor based on Fe(3)O(4) decorated carbon nanotube nanocomposites for environmental safety: Real sample analyses
title Fabrication of 3-methoxyphenol sensor based on Fe(3)O(4) decorated carbon nanotube nanocomposites for environmental safety: Real sample analyses
title_full Fabrication of 3-methoxyphenol sensor based on Fe(3)O(4) decorated carbon nanotube nanocomposites for environmental safety: Real sample analyses
title_fullStr Fabrication of 3-methoxyphenol sensor based on Fe(3)O(4) decorated carbon nanotube nanocomposites for environmental safety: Real sample analyses
title_full_unstemmed Fabrication of 3-methoxyphenol sensor based on Fe(3)O(4) decorated carbon nanotube nanocomposites for environmental safety: Real sample analyses
title_short Fabrication of 3-methoxyphenol sensor based on Fe(3)O(4) decorated carbon nanotube nanocomposites for environmental safety: Real sample analyses
title_sort fabrication of 3-methoxyphenol sensor based on fe(3)o(4) decorated carbon nanotube nanocomposites for environmental safety: real sample analyses
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5609863/
https://www.ncbi.nlm.nih.gov/pubmed/28938019
http://dx.doi.org/10.1371/journal.pone.0177817
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