Nitrogen-Doped Carbon Nanoparticles for Oxygen Reduction Prepared via a Crushing Method Involving a High Shear Mixer

The disposal of agricultural wastes such as fresh banana peels (BPs) is an environmental issue. In this work, fresh BPs were successfully transformed into nitrogen-doped carbon nanoparticles (N-CNPs) by using a high shear mixer facilitated crushing method (HSM-FCM) followed by carbonization under Ar atmosphere. Ammonia-activated N-CNPs (N-CNPs-NH(3)) were prepared via subsequent ammonia activation treatments at a high temperature. The as-prepared N-CNPs and N-CNPs-NH(3) materials both exhibited high surface areas (above 700 m(2)/g) and mean particle size of 50 nm. N-CNPs-NH(3) showed a relatively higher content of pyridinic and graphitic N compared to N-CNPs. In alkaline media, N-CNPs-NH(3) showed superior performances as an oxygen reduction reaction (ORR) catalyst (E(0) = −0.033 V, J = 2.4 mA/cm(2)) compared to N-CNPs (E(0) = 0.07 V, J = 1.8 mA/cm(2)). In addition, N-CNPs-NH(3) showed greater oxygen reduction stability and superior methanol crossover avoidance than a conventional Pt/C catalyst. This study provides a novel, simple, and scalable approach to valorize biomass wastes by synthesizing highly efficient electrochemical ORR catalysts.