ENDOR characterization of an iron–alkene complex provides insight into a corresponding organometallic intermediate of nitrogenase

A bio-organometallic intermediate, denoted PA, was previously trapped during the reduction of propargyl alcohol to allyl alcohol (AA) by nitrogenase, and a similar one was trapped during acetylene reduction, representing foundational examples of alkene binding to a metal center in biology. ENDOR spe...

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Detalles Bibliográficos
Autores principales: Horitani, Masaki, Grubel, Katarzyna, McWilliams, Sean F., Stubbert, Bryan D., Mercado, Brandon Q., Yu, Ying, Gurubasavaraj, Prabhuodeyara M., Lees, Nicholas S., Holland, Patrick L., Hoffman, Brian M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5620524/
https://www.ncbi.nlm.nih.gov/pubmed/28989623
http://dx.doi.org/10.1039/c7sc01602f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5620524/
https://www.ncbi.nlm.nih.gov/pubmed/28989623
http://dx.doi.org/10.1039/c7sc01602f

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