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Borylation of fluorinated arenes using the boron-centred nucleophile B(CN)(3) (2–) – a unique entry to aryltricyanoborates
The potassium salt of the boron-centred nucleophile B(CN)(3) (2–) (1) readily reacts with perfluorinated arenes, such as hexafluorobenzene, decafluorobiphenyl, octafluoronaphthalene and pentafluoropyridine, which results in KF and the K(+) salts of the respective borate anions with one {B(CN)(3)} un...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5620525/ https://www.ncbi.nlm.nih.gov/pubmed/28989626 http://dx.doi.org/10.1039/c7sc02249b |