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Enhancing the reactivity of nickel(ii) in hydrogen evolution reactions (HERs) by β-hydrogenation of porphyrinoid ligands

Fine-tuning of the porphyrin β-periphery is important for naturally occurring metal tetrapyrroles to exert diverse biological roles. Here we describe how this approach is also applied to design molecular catalysts, as exemplified by Ni(ii) porphyrinoids catalyzing the hydrogen evolution reaction (HE...

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Detalles Bibliográficos
Autores principales:	Wu, Zhuo-Yan, Wang, Teng, Meng, Yin-Shan, Rao, Yu, Wang, Bing-Wu, Zheng, Jie, Gao, Song, Zhang, Jun-Long
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5620542/ https://www.ncbi.nlm.nih.gov/pubmed/28989625 http://dx.doi.org/10.1039/c7sc02073b

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