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Enantioselective catalytic β-amination through proton-coupled electron transfer followed by stereocontrolled radical–radical coupling
A new mechanistic approach for the catalytic, enantioselective conjugate addition of nitrogen-based nucleophiles to acceptor-substituted alkenes is reported, which is based on a visible light induced and phosphate base promoted transfer of a single electron from a nitrogen nucleophile to a catalyst-...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5621506/ https://www.ncbi.nlm.nih.gov/pubmed/28989615 http://dx.doi.org/10.1039/c7sc02031g |